[Fc(NH)₂]Ru(PPh₃)₂

Base Information

• Chemical Name: [Fc(NH)₂]Ru(PPh₃)₂
• CAS No.: 1383970-54-4
• Molecular Formula: C₄₆H₄₀FeN₂P₂Ru
• Molecular Weight: 839.702
• Mol file: 1383970-54-4.mol

Synonyms:

Chemical Property of [Fc(NH)₂]Ru(PPh₃)₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fc(NH)₂]Ru(PPh₃)₂

There total 2 articles about [Fc(NH)₂]Ru(PPh₃)₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

[1,1'-diaminoferrocene]RuCl2(PPh3)2 (1383970-53-3) → [fc(NH)2]Ru(PPh3)2 (1383970-54-4)

Guidance literature:

With KOC(CH₃)3; In tetrahydrofuran; byproducts: KCl, (CH3)3COH; soln. of KOtBu (0.780 mmol) in THF added dropwise to soln. of FeRu compd. (0.390 mmol) in THF at -78°C, mixt. stirred for 1 h, warmed to room temp., stirred for 2 h; evapn. under vac., residue dissolved in toluene, soln. filtered through Celite, filtrate layered with pentane, crystals isolated; elem. anal.;

DOI:10.1039/c2dt31075a

Reference yield: 78.0%

[Fc(NH2)2]RuCl2(PPh3)2 (1383970-53-3) → [Fc(NH)2]Ru(PPh3)2 (1383970-54-4)

Guidance literature:

With potassium tert-butylate; Inert atmosphere; Schlenk technique;

DOI:10.1021/ic400773s

Reference yield: 69.0%

1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + [fc(NH)2]Ru(PPh3)2 (1383970-54-4) → [fc(NH)2]Ru(dppf) (1383970-56-6)

Guidance literature:

In toluene; byproducts: P(C6H5)3; soln. of bis-(PPh2)2-ferrocene (0.330 mmol) in toluene added to soln. ofFeRu compd. (0.275 mmol) in toluene under stirring, mixt. stirred at ro om temp. for 6.5 h; evapn. unde vac., residue washed with Et2O, soln. filtered through Celite with THF, filtrate layered with hexane; elem. anal.;

DOI:10.1039/c2dt31075a

upstream raw materials:

[1,1'-diaminoferrocene]RuCl₂(PPh₃)2

[Fc(NH₂)₂]RuCl₂(PPh₃)₂

Downstream raw materials:

[fc(NH)2]Ru(dppf)

[Fc(NH)₂]Ru(PMe₂Ph)₃

[Fc(NH)₂]Ru(PMe₂Ph)₂