C₅H₅Re(CO)2Fe(CO)3CC₆H₅SeC₆H₄CH₃

Base Information

• Chemical Name: C₅H₅Re(CO)2Fe(CO)3CC₆H₅SeC₆H₄CH₃
• CAS No.: 349606-53-7
• Molecular Formula: C₂₄H₁₇FeO₅ReSe
• Molecular Weight: 706.41
• Mol file: 349606-53-7.mol

Synonyms:

Chemical Property of C₅H₅Re(CO)2Fe(CO)3CC₆H₅SeC₆H₄CH₃

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of C₅H₅Re(CO)2Fe(CO)3CC₆H₅SeC₆H₄CH₃

There total 1 articles about C₅H₅Re(CO)2Fe(CO)3CC₆H₅SeC₆H₄CH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

selenium (7782-49-2) + triiron dodecarbonyl (17685-52-8) + [(η(5)-C5H5)(CO)2Re*CC6H5]BBr4 + para-methylphenylmagnesium bromide (4294-57-9) → tricarbonylcyclopentadienylrhenium + (μ-p-MeC6H4Se)2Fe2(CO)6 (172367-46-3,350039-26-8) + C5H5Re(CO)2Fe(CO)3CC6H5SeC6H4CH3 (349606-53-7)

Guidance literature:

In tetrahydrofuran; (N2); stirring a mixt. of selenium and magnesium compd. in THF at room temp. for 20 min, addn. of iron carbonyl, stirring at room temp. for 30 min, cooling to -100°C, poured to rhenium complex, warming to -80°C, stirring for 6 h; evapn. at -50 to -40°C, column chromy (Al2O3, petroleum ether, petroleum ether/CH2Cl2 20:1, petroleum ether/CH2Cl2/Et2O 10:1:1), evapn., recrystn. (petroleum ether/CH2Cl2, -80°C); elem. anal.;

DOI:10.1021/om001035a

upstream raw materials:

selenium

triiron dodecarbonyl

para-methylphenylmagnesium bromide