[CpCoI₂((2,4,6-tri-tert-butylphenyl)phosphine)]

Base Information

Chemical Name:[CpCoI₂((2,4,6-tri-tert-butylphenyl)phosphine)]
CAS No.:532932-56-2
Molecular Formula:C₂₃H₃₆CoI₂P
Molecular Weight:656.315
Hs Code.:

[CpCoI<sub>2</sub>((2,4,6-tri-tert-butylphenyl)phosphine)]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [CpCoI₂((2,4,6-tri-tert-butylphenyl)phosphine)]

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Technology Process of [CpCoI₂((2,4,6-tri-tert-butylphenyl)phosphine)]

There total 1 articles about [CpCoI₂((2,4,6-tri-tert-butylphenyl)phosphine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: cyclopentadienyldiiodocobalt(III)

: 83115-12-2
(2,4,6-tri-tert-butylphenyl)phosphine

: 532932-56-2
[CpCoI₂((2,4,6-tri-tert-butylphenyl)phosphine)]

Guidance literature:: In dichloromethane; (N2 or Ar); addn. of soln. of (t-Bu)3C6H2PH2 in CH2Cl2 to suspn. of ((C5H5)CoI2)(n) in CH2Cl2, stirring for 1 h at room temp.; filtration, concn., addn. of n-pentane, cooling to 0°C, pptn., filtration, washing with cold n-pentane, drying in vac.;
DOI:10.1021/om0208624

Reference yield: 42.0%

: 532932-56-2
[CpCoI₂((2,4,6-tri-tert-butylphenyl)phosphine)]

: 603-35-0
triphenylphosphine

: 109-66-0,8031-35-4,9078-70-0
pentane

: 532932-59-5
[CpCo(triphenylphosphine)((2,4,6-tri-tert-butylphenyl)phosphinidene)]*C₅H₁₂

Guidance literature:: With DBU; In dichloromethane; toluene; byproducts: DBU*HI; (N2 or Ar); addn. slowly of soln. of ((t-Bu)3C6H2PH2)CpCoI2 in CH2Cl2 tostirred soln. of DBU (2 equiv.) and PPh3 in toluene at 0°C; warm ing to room temp., stirring for 5 min; removal of solvents, extn. into n-pentane, filtration, concn., crystn. at -20°C, elem. anal.;
DOI:10.1021/om0208624

Reference yield: 10.0%

: 532932-56-2
[CpCoI₂((2,4,6-tri-tert-butylphenyl)phosphine)]

: 201230-82-2
carbon monoxide

: (Z)-Cp(CO)Co((2,4,6-tri-tert-butylphenyl)phosphinidene)

Guidance literature:: With DBU; In dichloromethane; toluene; byproducts: DBU*HI; (N2 or Ar); treatment of soln. of ((t-Bu)3C6H2PH2)CpCoI2 in CH2Cl2 with DBU (2 equiv.) and CO in toluene at 0°C; warming to room temp., stirring for 5 min; not isolated, monitoring by NMR;
DOI:10.1021/om0208624