[Pt(5-phenyl-2-(2-thienyl)cyclopenteno[c]pyridine^(1-))Cl(dimethylsulfoxide)]

Base Information

• Chemical Name: [Pt(5-phenyl-2-(2-thienyl)cyclopenteno[c]pyridine^(1-))Cl(dimethylsulfoxide)]
• CAS No.: 1042163-01-8
• Molecular Formula: C₂₀H₂₀ClNOPtS₂
• Molecular Weight: 585.05
• Mol file: 1042163-01-8.mol

Synonyms:

Chemical Property of [Pt(5-phenyl-2-(2-thienyl)cyclopenteno[c]pyridine^(1-))Cl(dimethylsulfoxide)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt(5-phenyl-2-(2-thienyl)cyclopenteno[c]pyridine^(1-))Cl(dimethylsulfoxide)]

There total 1 articles about [Pt(5-phenyl-2-(2-thienyl)cyclopenteno[c]pyridine^(1-))Cl(dimethylsulfoxide)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

potassium tetrachloroplatinate(II) (10025-99-7) + 5-phenyl-2-(2-thienyl)cyclopenteno[c]pyridine (1041285-76-0) + dimethyl sulfoxide (67-68-5,8070-53-9) → [Pt(5-phenyl-2-(2-thienyl)cyclopenteno[c]pyridine(1-))Cl(dimethylsulfoxide)] (1042163-01-8)

Guidance literature:

In water; acetic acid; to soln. ligand in AcOH aq. soln. K2(PtCl4) was added and heated to 70°C for 24 h under N2 atm., ppt. was filtered off, washed with AcOH and EtOH and dried in vacuo, DMSO was added and heated under reflux for 10 min; solvent was removed in vacuo, residue was dissolved in CH2Cl2, column chromy. on silica (CH2Cl2); elem. anal.;

DOI:10.1021/ic802401j

Reference yield: 54.0%

sodium acetylacetonate monohydrate (86891-03-4) + [Pt(5-phenyl-2-(2-thienyl)cyclopenteno[c]pyridine(1-))Cl(dimethylsulfoxide)] (1042163-01-8) → [Pt(5-phenyl-2-(2-thienyl)cyclopenteno[c]pyridine(1-))(acetylacetonato)] (1042163-03-0)

Guidance literature:

In acetone; mixt. Pt complex, Na(acac)*H2O and acetone was stirred at 50°C for 12 h; react. mixt. was diluted with water, ppt. was filtered off, washed with water and dried in vacuo; elem. anal.;

DOI:10.1021/ic802401j

upstream raw materials:

potassium tetrachloroplatinate(II)

5-phenyl-2-(2-thienyl)cyclopenteno[c]pyridine

dimethyl sulfoxide

Downstream raw materials:

[Pt(5-phenyl-2-(2-thienyl)cyclopenteno[c]pyridine^(1-))(acetylacetonato)]