1-Methyl-cyclohex-3-enecarbaldehyde oxime

Base Information

• Chemical Name: 1-Methyl-cyclohex-3-enecarbaldehyde oxime
• CAS No.: 112622-03-4
• Molecular Formula: C₈H₁₃NO
• Molecular Weight: 139.197
• Mol file: 112622-03-4.mol

Synonyms:

Chemical Property of 1-Methyl-cyclohex-3-enecarbaldehyde oxime

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-Methyl-cyclohex-3-enecarbaldehyde oxime

There total 1 articles about 1-Methyl-cyclohex-3-enecarbaldehyde oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1-methyl-3-cyclohexene-1-carboxaldehyde (931-96-4) → 1-Methyl-cyclohex-3-enecarbaldehyde oxime (112622-03-4,112622-04-5)

Guidance literature:

With hydroxylamine hydrochloride; sodium carbonate; In ethanol; water; for 3h; Ambient temperature;

DOI:10.1021/jo00240a006

Reference yield:

1-Methyl-cyclohex-3-enecarbaldehyde oxime (112622-03-4,112622-04-5) → N-(1-Methyl-cyclohex-3-enylmethyl)-hydroxylamine

Guidance literature:

With hydrogenchloride; borane pyridine; In ethanol; for 0.333333h; Ambient temperature;

DOI:10.1021/jo00240a006

Reference yield:

1-Methyl-cyclohex-3-enecarbaldehyde oxime (112622-03-4,112622-04-5) → N,O-bis(methoxycarbonyl)-N-<(1-methyl-3-cyclohexenyl)methyl>hydroxylamine (104407-25-2)

Guidance literature:

Multi-step reaction with 2 steps

1: BH₃-pyridine, 10percent HCl / ethanol / 0.33 h / Ambient temperature

2: Et₃N / diethyl ether / 1.5 h / Ambient temperature

With hydrogenchloride; borane pyridine; triethylamine; In diethyl ether; ethanol;

DOI:10.1021/jo00240a006

upstream raw materials:

1-methyl-3-cyclohexene-1-carboxaldehyde

Downstream raw materials:

N,O-bis(methoxycarbonyl)-N-<(1-methyl-3-cyclohexenyl)methyl>hydroxylamine

Refernces