benzylbromobis[2,4,6-triisopropylphenyl]tin(IV)

Base Information

Chemical Name:benzylbromobis[2,4,6-triisopropylphenyl]tin(IV)
CAS No.:887127-44-8
Molecular Formula:C₃₇H₅₃BrSn
Molecular Weight:696.442
Hs Code.:

Synonyms:

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Chemical Property of benzylbromobis[2,4,6-triisopropylphenyl]tin(IV)

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Technology Process of benzylbromobis[2,4,6-triisopropylphenyl]tin(IV)

There total 1 articles about benzylbromobis[2,4,6-triisopropylphenyl]tin(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 1589-82-8
phenylmagnesium bromide

: 7789-67-5
stannic bromide

: 108894-99-1
(2,4,6-triisopropylphenyl)magnesium bromide

: 887127-44-8
benzylbromobis[2,4,6-triisopropylphenyl]tin(IV)

Guidance literature:: In tetrahydrofuran; (under N2, Schlenk); soln. of ligand in THF added dropwise to stirred soln. of SnBr4 in THF at 0°C, refluxed for 16 h, cooled to 0°C, THF soln. of benzylmagnesium bromide added, refluxed for 5 h, cooledto room temp., stirred overnight; quenched with H2O, aq. soln. of HBr, washed with H2O, NaHCO3, H2O, driedover Na2SO4, solvent removed, dissolved in hexane, stored at -20.degree .C overnight; elem. anal.;
DOI:10.1016/j.jorganchem.2005.12.011

Reference yield: 70.0%

: 887127-44-8
benzylbromobis[2,4,6-triisopropylphenyl]tin(IV)

: 1730-25-2
allylmagnesium bromide

: 887127-45-9
allylbenzylbis[2,4,6-triisopropylphenyl]tin(IV)

Guidance literature:: In tetrahydrofuran; toluene; (under N2, Schlenk); soln. of allylmagnesium bromide in THF added dropwise to stirred soln. of Sn-compound in toluene at 0°C, refluxed for 2 d; quenched with H2O, aq. soln. of HBr, washed with H2O, NaHCO3, H2O, driedover MgSO4, solvent removed, crystd. from MeOH/hexane at -20°C; elem. anal.;
DOI:10.1016/j.jorganchem.2005.12.011

Reference yield:

: 887127-44-8
benzylbromobis[2,4,6-triisopropylphenyl]tin(IV)

: 887127-49-3
[benzylbis[2,4,6-triisopropylphenyl]tin(IV)][B(C₆F₅)4]

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran; toluene

2: triethylsilane / benzene-d6

With triethylsilane; In tetrahydrofuran; benzene-d6; toluene;
DOI:10.1016/j.jorganchem.2005.12.011