(Me₃SiNC(Ph)N(CH₂)3NC(Ph)NSiMe₃)YCl(THF)2

Base Information

• Chemical Name: (Me₃SiNC(Ph)N(CH₂)3NC(Ph)NSiMe₃)YCl(THF)2
• CAS No.: 330195-26-1
• Molecular Formula: C₃₁H₅₀ClN₄O₂Si₂Y
• Molecular Weight: 691.293
• Mol file: 330195-26-1.mol

Synonyms:

Chemical Property of (Me₃SiNC(Ph)N(CH₂)3NC(Ph)NSiMe₃)YCl(THF)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Me₃SiNC(Ph)N(CH₂)3NC(Ph)NSiMe₃)YCl(THF)2

There total 1 articles about (Me₃SiNC(Ph)N(CH₂)3NC(Ph)NSiMe₃)YCl(THF)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

yttrium trichloride*3tetrahydrofuran + 2Li(1+)*((CH3)3SiNC(C6H5)N)2(CH2)3(2-)*0.5C4H8O=((CH3)3SiN(Li)C(C6H5)N)2(CH2)3*0.5C4H8O → ((CH3)3SiNCC6H5NCH2)2CH2Y(C4H8O)2Cl (330195-26-1)

Guidance literature:

In tetrahydrofuran; a suspn. in THF was stirred overnight (N2); the solvent was removed in vac., stirred with pentane, evapd., extd. with pentane, reduced in vol., ccoled to -30°C; elem. anal.;

DOI:10.1021/om0008124

Reference yield: 85.0%

1,2-dimethoxyethane (110-71-4) + (Me3SiNC(Ph)N(CH2)3NC(Ph)NSiMe3)YCl(THF)2 (330195-26-1) + sodium 2,6-dimethylphenolate (16081-16-6) → (Me3SiNC(Ph)N(CH2)3NC(Ph)NSiMe3)Y[O2,6-(Me)2C6H3](DME) (1431150-01-4)

Guidance literature:

(Me₃SiNC(Ph)N(CH₂)3NC(Ph)NSiMe₃)YCl(THF)2; sodium 2,6-dimethylphenolate; In tetrahydrofuran; at 20 ℃; Inert atmosphere; Schlenk technique;

1,2-dimethoxyethane;

DOI:10.1039/c3dt33069a

Reference yield: 83.0%

1,2-dimethoxyethane (110-71-4) + (Me3SiNC(Ph)N(CH2)3NC(Ph)NSiMe3)YCl(THF)2 (330195-26-1) + sodium 2,6-diisopropylphenate (113981-41-2) → (Me3SiNC(Ph)N(CH2)3NC(Ph)NSiMe3)Y[O2,6-(iPr)2C6H3](DME) (1431150-06-9)

Guidance literature:

(Me₃SiNC(Ph)N(CH₂)3NC(Ph)NSiMe₃)YCl(THF)2; sodium 2,6-diisopropylphenate; In tetrahydrofuran; at 20 ℃; Inert atmosphere; Schlenk technique;

1,2-dimethoxyethane;

DOI:10.1039/c3dt33069a

Downstream raw materials:

((CH₃)3SiNCC₆H₅NCH₂)2CH₂Y(C₄H₈O)CH(Si(CH₃)3)2

[((Me3SiNC(C6H5)N)2C3H6)Y(η3-BH4)(dimethoxyethane)]

Y((CH₃)3SiNCC₆H₅NCH₂)2CH₂(CH₃OCH₂CH₂OCH₃)(NHC₆H₃(CH(CH₃)2)2)

(Me₃SiNC(Ph)N(CH₂)3NC(Ph)NSiMe₃)Y[O₂,6-(Me)2C₆H₃](DME)