bis(undecamethylcyclohexasilanyl)bis(p-methylphenyl)stannane

Base Information

• Chemical Name: bis(undecamethylcyclohexasilanyl)bis(p-methylphenyl)stannane
• CAS No.: 299438-06-5
• Molecular Formula: C₃₆H₈₀Si₁₂Sn
• Molecular Weight: 968.767
• Mol file: 299438-06-5.mol

Synonyms:

Chemical Property of bis(undecamethylcyclohexasilanyl)bis(p-methylphenyl)stannane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of bis(undecamethylcyclohexasilanyl)bis(p-methylphenyl)stannane

There total 1 articles about bis(undecamethylcyclohexasilanyl)bis(p-methylphenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

di(p-tolyl)tin dichloride (32538-29-7) + potassium(I) undecamethylcyclohexasilanide → bis(undecamethylcyclohexasilanyl)bis(p-methylphenyl)stannane (299438-06-5)

Guidance literature:

In tetrahydrofuran; ethanol; diethylene glycol dimethyl ether; byproducts: KCl; in inert gas atmosphere to stirred THF-soln. of (p-MePh)2SnCl2 at -50 °C diglyme-soln. of KSi6(CH3)11 added dropwise in 1 h, stirred 12 hs; solvent distd. off in vac., addn. of hexane, residue filtered, hexane distd. off in vac., addn. of ethanol, soln. stored at -20 °C 24 hs,crystals filtered, recrystd. from acetone, elem. anal.;

DOI:10.1016/S0022-328X(00)00249-7

upstream raw materials:

di(p-tolyl)tin dichloride