N,N''-bis(2,2'-bipyridin-6-ylmethyl)-N,,N',N''-tri(toluene-p-sulfonyl)diethylenetriamine

Base Information

• Chemical Name: N,N''-bis(2,2'-bipyridin-6-ylmethyl)-N,,N',N''-tri(toluene-p-sulfonyl)diethylenetriamine
• CAS No.: 144809-32-5
• Molecular Formula: C₄₇H₄₇N₇O₆S₃
• Molecular Weight: 902.131
• Mol file: 144809-32-5.mol

Synonyms:

Chemical Property of N,N''-bis(2,2'-bipyridin-6-ylmethyl)-N,,N',N''-tri(toluene-p-sulfonyl)diethylenetriamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N''-bis(2,2'-bipyridin-6-ylmethyl)-N,,N',N''-tri(toluene-p-sulfonyl)diethylenetriamine

There total 1 articles about N,N''-bis(2,2'-bipyridin-6-ylmethyl)-N,,N',N''-tri(toluene-p-sulfonyl)diethylenetriamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,4,7-tritosyl-1,4,7-triazaheptane (56187-04-3) + 6-(chloromethyl)-2,2’-bipyridine (82740-65-6) → N,N''-bis(2,2'-bipyridin-6-ylmethyl)-N,,N',N''-tri(toluene-p-sulfonyl)diethylenetriamine (144809-32-5)

Guidance literature:

With sodium methylate; Yield given. Multistep reaction; 1) methanol, reflux, 1.5 h, 2) DMF, 70 deg C, 4 h;

DOI:10.1039/DT9920002667

Reference yield: 69.0%

silver trifluoromethanesulfonate (2923-28-6) + N,N''-bis(2,2'-bipyridin-6-ylmethyl)-N,,N',N''-tri(toluene-p-sulfonyl)diethylenetriamine (144809-32-5) → Ag(1+)*{C5NH4C5NH3CH2N(SO2C6H4CH3)CH2CH2}2NSO2C6H4CH3*CF3SO3(1-)=Ag(CF3SO3){(C10N2H7CH2N(SO2C7H7)(CH2)2)2NSO2C7H7}

Guidance literature:

In acetonitrile; addn. of Ag-salt soln. to ligand soln., stirring at room temp. for 1 h in the dark (N2); evapn. (vac.), addn. of Et2O, pptn., filtration, washing (Et2O), recrystn. (MeCN); elem. anal.;

DOI:10.1039/DT9920002667

upstream raw materials:

1,4,7-tritosyl-1,4,7-triazaheptane

6-(chloromethyl)-2,2’-bipyridine