(N(2-PPh₂-4-Me-C₆H₃)2)IrMe(I)(THF)

Base Information

• Chemical Name: (N(2-PPh₂-4-Me-C₆H₃)2)IrMe(I)(THF)
• CAS No.: 1255934-58-7
• Molecular Formula: C₄₃H₄₃IIrNOP₂
• Molecular Weight: 970.893
• Mol file: 1255934-58-7.mol

Synonyms:

Chemical Property of (N(2-PPh₂-4-Me-C₆H₃)2)IrMe(I)(THF)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (N(2-PPh₂-4-Me-C₆H₃)2)IrMe(I)(THF)

There total 1 articles about (N(2-PPh₂-4-Me-C₆H₃)2)IrMe(I)(THF) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + (N(2-PPh2-4-Me-C6H3)2)Ir(COE) (1255934-46-3) + methyl iodide (74-88-4) → (N(2-PPh2-4-Me-C6H3)2)IrMe(I)(THF) (1255934-58-7)

Guidance literature:

In tetrahydrofuran; (N2); a soln. of CH3I added to a suspn. of Ir complex, reacted for 1 h at ambient temp.; filtered, evapd. (vac.), crystd. by diffusion of pentane into a concd. CH2Cl2 soln. at -30°C; elem. anal.;

DOI:10.1039/b925856f

Reference yield: 48.0%

(m,m'-dimethyl)phenylsilane + (N(2-PPh2-4-Me-C6H3)2)IrMe(I)(THF) (1255934-58-7) → (N(2-PPh2-4-Me-C6H3)2)IrI(SiH2-3,5-Me2C6H3) (1255934-75-8)

Guidance literature:

In toluene; byproducts: CH4, C4H8O; (N2); a soln. of Si compd. added to a soln. of Ir complex, stirred for 30 min at ambient temp.; evapd., recrystd. from C6H5F/pentane at -10°C; elem. anal.;

DOI:10.1039/b925856f

upstream raw materials:

tetrahydrofuran

(N(2-PPh₂-4-Me-C₆H₃)2)Ir(COE)

methyl iodide

Downstream raw materials:

(N(2-PPh₂-4-Me-C₆H₃)2)IrI(SiH₂-3,5-Me₂C₆H₃)