<3aR-<3aα,4α,5β(R),6β,7β,7aα>>-4-benzyloxy-6,7-epoxy-5-(1-phenylethoxy)-hexahydro-2,2-dimethylbenzo-1,3-dioxole

Base Information

Chemical Name:<3aR-<3aα,4α,5β(R),6β,7β,7aα>>-4-benzyloxy-6,7-epoxy-5-(1-phenylethoxy)-hexahydro-2,2-dimethylbenzo-1,3-dioxole
CAS No.:130633-27-1
Molecular Formula:C₂₄H₂₈O₅
Molecular Weight:396.483
Hs Code.:

<3aR-<3aα,4α,5β(R),6β,7β,7aα>>-4-benzyloxy-6,7-epoxy-5-(1-phenylethoxy)-hexahydro-2,2-dimethylbenzo<d>-1,3-dioxole

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Chemical Property of <3aR-<3aα,4α,5β(R),6β,7β,7aα>>-4-benzyloxy-6,7-epoxy-5-(1-phenylethoxy)-hexahydro-2,2-dimethylbenzo-1,3-dioxole

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Technology Process of <3aR-<3aα,4α,5β(R),6β,7β,7aα>>-4-benzyloxy-6,7-epoxy-5-(1-phenylethoxy)-hexahydro-2,2-dimethylbenzo-1,3-dioxole

There total 20 articles about <3aR-<3aα,4α,5β(R),6β,7β,7aα>>-4-benzyloxy-6,7-epoxy-5-(1-phenylethoxy)-hexahydro-2,2-dimethylbenzo-1,3-dioxole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 130633-26-0,130697-92-6
<1S-<1α,2α,3β,4α(R),5α,6α>>-3-benzyloxy-5,6-epoxy-4-(1-phenylethoxy)cyclohexane-1,2-diol

: 77-76-9
2,2-dimethoxy-propane

: 130633-27-1,130697-93-7
<3aS-<3aα,4α,5β(R),6β,7β,7aα>>-4-benzyloxy-6,7-epoxy-5-(1-phenylethoxy)-hexahydro-2,2-dimethylbenzo-1,3-dioxole

Guidance literature:: With camphor-10-sulfonic acid; for 4h; Ambient temperature;

Reference yield: 89.0%

: 130633-26-0,130697-92-6
<1R-<1α,2α,3β,4α(R),5α,6α>>-3-benzyloxy-5,6-epoxy-4-(1-phenylethoxy)cyclohexane-1,2-diol

: 77-76-9
2,2-dimethoxy-propane

: 130633-27-1,130697-93-7
<3aR-<3aα,4α,5β(R),6β,7β,7aα>>-4-benzyloxy-6,7-epoxy-5-(1-phenylethoxy)-hexahydro-2,2-dimethylbenzo-1,3-dioxole

Guidance literature:: With camphor-10-sulfonic acid; for 16h; Ambient temperature;

Reference yield:

: 1517-69-7
(R)-1-phenylethanol

: 130633-27-1,130697-93-7
<3aS-<3aα,4α,5β(R),6β,7β,7aα>>-4-benzyloxy-6,7-epoxy-5-(1-phenylethoxy)-hexahydro-2,2-dimethylbenzo-1,3-dioxole

Guidance literature:: Multi-step reaction with 5 steps

1: HBF₄*OEt₂ / CH₂Cl₂ / 0.5 h / Ambient temperature

2: 81 percent / Ag₂O / dimethylformamide / 96 h / Ambient temperature

3: 97 percent / Et₃N, H₂O / methanol / 70 h / Ambient temperature

4: 72 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 48 h / Ambient temperature

5: 91 percent / camphorsulphonic acid*H₂O / 4 h / Ambient temperature

With tetrafluoroboric acid diethyl ether; camphor-10-sulfonic acid; water; triethylamine; 3-chloro-benzenecarboperoxoic acid; silver(l) oxide; In methanol; dichloromethane; N,N-dimethyl-formamide;