triphenylstibine oxide

Base Information

• Chemical Name: triphenylstibine oxide
• CAS No.: 102614-53-9
• Molecular Formula: C₃₆H₃₀O₂Sb₂
• Molecular Weight: 738.133
• Mol file: 102614-53-9.mol

Synonyms:

Chemical Property of triphenylstibine oxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triphenylstibine oxide

There total 1 articles about triphenylstibine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

methoxytetraphenylstibane (14090-94-9) → triphenylstibine oxide (102614-53-9)

Guidance literature:

In xylene; educt was suspd. in xylene and heated at 60-70°C for 6 days under N2; xylene was removed, liquid was cooled to 0°C, ppt. was sepd.; MP, X-ray;

DOI:10.1021/ja00274a059

Reference yield: 98.0%

triphenylantimony oxide dimer (102614-53-9) + 2-hydroxyethanesulfonic acid (107-36-8) → (C6H5)3Sb(O3SCH2CH2OH)2 (112100-67-1)

Guidance literature:

In acetone; suspending Me3Sb(OH)2 in a mixt. of acetone and 2,2-dimethoxypropane, adding the sulfonic acid, pptn.; filtering by suction, washing (abs. acetone or ether), drying (desiccator, silica gel); elem. anal.;

Reference yield: 93.0%

triphenylantimony oxide dimer (102614-53-9) + benzenesulfonic acid (98-11-3) → (C6H5)3Sb(O3SC6H5)2 (112100-68-2)

Guidance literature:

In acetone; suspending Me3Sb(OH)2 in a mixt. of acetone and 2,2-dimethoxypropane, adding the sulfonic acid, pptn.; filtering by suction, washing (abs. acetone or ether), drying (desiccator, silica gel); elem. anal.;

upstream raw materials:

methoxytetraphenylstibane

Downstream raw materials:

(C₆H₅)3Sb(O₃SC₆H₃(NO₂)2)2

(C₆H₅)3Sb(O₃SCH₃)2

(C₆H₅)3Sb(O₃SCH₂CH₂OH)2

triphenylantimony di(p-toluenesulfonate)