Zn(II)-5-[4-(hydroxymethyl)phenyl]-10,15,20-tri-ptolylporphyrin

Base Information

• Chemical Name: Zn(II)-5-[4-(hydroxymethyl)phenyl]-10,15,20-tri-ptolylporphyrin
• CAS No.: 784151-82-2
• Molecular Formula: C₄₈H₃₆N₄OZn
• Molecular Weight: 750.23
• Mol file: 784151-82-2.mol

Synonyms:

Chemical Property of Zn(II)-5-[4-(hydroxymethyl)phenyl]-10,15,20-tri-ptolylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Zn(II)-5-[4-(hydroxymethyl)phenyl]-10,15,20-tri-ptolylporphyrin

There total 6 articles about Zn(II)-5-[4-(hydroxymethyl)phenyl]-10,15,20-tri-ptolylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

zinc(II) acetate dihydrate (5970-45-6) + 5-(4-hydroxymethylphenyl)-10,15,20-tris(4-methylphenyl)porphyrin (121869-50-9) → Zn(II)-5-[4-(hydroxymethyl)phenyl]-10,15,20-tri-ptolylporphyrin (784151-82-2)

Guidance literature:

In tetrahydrofuran; for 4h; Reflux;

DOI:10.1021/op0502553

Reference yield:

zinc(II) 5-(4-carboxyphenyl)-10,15,20-tris(4-methylphenyl)porphyrin (91879-46-8) → Zn(II)-5-[4-(hydroxymethyl)phenyl]-10,15,20-tri-ptolylporphyrin (784151-82-2)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at -80 - 20 ℃; for 1.16667h;

DOI:10.1021/jo3000833

Reference yield:

5-(4-carboxyphenyl)-10,15,20-tris(4-methylphenyl) porphyrin (61449-63-6) → Zn(II)-5-[4-(hydroxymethyl)phenyl]-10,15,20-tri-ptolylporphyrin (784151-82-2)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium acetate; zinc(II) acetate dihydrate / methanol; chloroform / 2 h / 75 °C

2: lithium aluminium tetrahydride / tetrahydrofuran / 1.17 h / -80 - 20 °C

With lithium aluminium tetrahydride; sodium acetate; zinc(II) acetate dihydrate; In tetrahydrofuran; methanol; chloroform;

DOI:10.1021/jo3000833

upstream raw materials:

5-(4-carboxyphenyl)-10,15,20-tris(4-methylphenyl) porphyrin

zinc(II) 5-(4-carboxyphenyl)-10,15,20-tris(4-methylphenyl)porphyrin

4-methyl-benzaldehyde

4-Carboxybenzaldehyde

Downstream raw materials:

5-(4-hydroxymethylphenyl)-10,15,20-tris(4-methylphenyl)porphyrin