[(η5-methyldiphenylphosphonium cyclopentadienylide)Mo(CO)3]

Base Information

• Chemical Name: [(η5-methyldiphenylphosphonium cyclopentadienylide)Mo(CO)3]
• CAS No.: 934000-51-8
• Molecular Formula: C₂₁H₁₇MoO₃P
• Molecular Weight: 444.278
• Mol file: 934000-51-8.mol

Synonyms:

Chemical Property of [(η5-methyldiphenylphosphonium cyclopentadienylide)Mo(CO)3]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η5-methyldiphenylphosphonium cyclopentadienylide)Mo(CO)3]

There total 1 articles about [(η5-methyldiphenylphosphonium cyclopentadienylide)Mo(CO)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

methyldiphenylphosphonium cyclopentadienylide (58109-59-4) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → [(η5-methyldiphenylphosphonium cyclopentadienylide)Mo(CO)3] (934000-51-8)

Guidance literature:

In diethylene glycol dimethyl ether; (Ar); refluxing soln. of molybdenum compd. and phosphorus compd. in diglyme for 3 h; cooling, filtration, washing solid with diglyme, addn. of hexane to filtrate, collecting precipitate, washing with hexane, drying in vac., elem.anal.;

DOI:10.1021/om070018j

Reference yield: 54.0%

[(η5-methyldiphenylphosphonium cyclopentadienylide)Mo(CO)3] (934000-51-8) + iodine (7553-56-2,12190-71-5,8031-47-8) → [(η5-C5H4PMePh2)MoI(CO)3]I (934000-53-0)

Guidance literature:

In dichloromethane; Irradiation (UV/VIS); (Ar); addn. of soln. of iodine in CH2Cl2 to soln. of molybdenum compd. in CH2Cl2, stirring for 30 min; filtration, evapn., elem. anal.;

DOI:10.1021/om070018j

Reference yield:

[(η5-methyldiphenylphosphonium cyclopentadienylide)Mo(CO)3] (934000-51-8) → [Mo(η5-methyldiphenylphosphoniumcyclopentadienylide)(CO)3]2(2+) (959934-28-2)

Guidance literature:

With (CH₃CH₂CH₂CH₂)4NB(C₆F₅)4; In dichloromethane; Electrolysis; (inert atm.); electrolysis of 3.0 mM soln. of molybdenum in CH2Cl2 at 0.15 V at 298 K in presence of 0.05 M tetrabutylammonium salt; not isolated, IR monitoring;

DOI:10.1021/om700688p

upstream raw materials:

methyldiphenylphosphonium cyclopentadienylide

molybdenum hexacarbonyl

Downstream raw materials:

[(η5-C5H4PMePh2)MoI(CO)3]I

[Mo(η5-methyldiphenylphosphoniumcyclopentadienylide)(CO)3]2(2+)