(1,2-bis(diphenylphosphino)ethane)Rh(PEt₃)[N(C₆H₄COOCH₃)CH(Ph)(p-tolyl)]

Base Information

• Chemical Name: (1,2-bis(diphenylphosphino)ethane)Rh(PEt₃)[N(C₆H₄COOCH₃)CH(Ph)(p-tolyl)]
• CAS No.: 777856-75-4
• Molecular Formula: C₅₄H₅₉NO₂P₃Rh
• Molecular Weight: 949.895
• Mol file: 777856-75-4.mol

Synonyms:

Chemical Property of (1,2-bis(diphenylphosphino)ethane)Rh(PEt₃)[N(C₆H₄COOCH₃)CH(Ph)(p-tolyl)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (1,2-bis(diphenylphosphino)ethane)Rh(PEt₃)[N(C₆H₄COOCH₃)CH(Ph)(p-tolyl)]

There total 1 articles about (1,2-bis(diphenylphosphino)ethane)Rh(PEt₃)[N(C₆H₄COOCH₃)CH(Ph)(p-tolyl)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

(1,2-bis(diphenylphosphino)ethane)Rh(pyridine)(p-tolyl) (676563-20-5) + N-benzylidene (4-carbomethoxy) aniline (4112-09-8) + triethylphosphine (554-70-1) → (1,2-bis(diphenylphosphino)ethane)Rh(PEt3)[N(C6H4COOCH3)CH(Ph)(p-tolyl)] (777856-75-4,777940-96-2)

Guidance literature:

In toluene; (inert atm.); addn. of toluene to a mixt. of rhodium complex and ligand,stirring for 5 min at room temp., addn. of phosphine; concn., addn. of Et2O, layering with pentane, standing overnight at roomtemp., sepn., washing ppt. with pentane, drying in vac.; elem. anal.;

DOI:10.1021/om0496582

upstream raw materials:

(1,2-bis(diphenylphosphino)ethane)Rh(pyridine)(p-tolyl)

N-benzylidene (4-carbomethoxy) aniline

triethylphosphine

Refernces