NiBr(2-Br-4,5-F₂C₆D₂)(PEt₃)2

Base Information

• Chemical Name: NiBr(2-Br-4,5-F₂C₆D₂)(PEt₃)2
• CAS No.: 879279-77-3
• Molecular Formula: C₁₈H₃₂Br₂F₂NiP₂
• Molecular Weight: 568.879
• Mol file: 879279-77-3.mol

Synonyms:

Chemical Property of NiBr(2-Br-4,5-F₂C₆D₂)(PEt₃)2

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of NiBr(2-Br-4,5-F₂C₆D₂)(PEt₃)2

There total 1 articles about NiBr(2-Br-4,5-F₂C₆D₂)(PEt₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

1,2-dibromo-3,6-dideuterio-4,5-difluorobenzene (879279-76-2) + bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + triethylphosphine (554-70-1) → NiBr(2-Br-4,5-F2C6D2)(PEt3)2 (879279-77-3)

Guidance literature:

In pentane; (N2); P(C2H5)3 added to a suspn. of Ni complex at 0°C, a soln. ofC6(2)H2F2Br2 added, stirred for 10 min at 0°C and for 4 h at roo m temp.; evapd. (vac.), extd. (pentane), filtered, concd., pptd. at -40°C;elem. anal.;

DOI:10.1021/ja067112w

upstream raw materials:

1,2-dibromo-3,6-dideuterio-4,5-difluorobenzene

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

triethylphosphine