2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-ethylimidazole

Base Information

• Chemical Name: 2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-ethylimidazole
• CAS No.: 902138-01-6
• Molecular Formula: C₂₂H₂₇N₂OPS
• Molecular Weight: 398.509
• Mol file: 902138-01-6.mol

Synonyms:

Chemical Property of 2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-ethylimidazole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-ethylimidazole

There total 1 articles about 2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-ethylimidazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

1-ethyl-2-formylimidazole (111851-98-0) + bis(2-phenylethyl)phosphane sulfide → 2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-ethylimidazole (902138-01-6)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 24h;

DOI:10.1007/s10593-005-0150-3

Reference yield: 99.0%

2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-ethylimidazole (902138-01-6) + cadmium(II) chloride (10108-64-2) → (2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-ethylimidazole)dichlorocadmium

Guidance literature:

In acetone; org. ligand and CdCl2 mixed in anhyd. acetone (20-25°C); kept (8 h); pptd. with ether; filtered; washed with acetone-ether mixt. (1:1); dried (vac.); elem. anal.;

DOI:10.1134/S1070328408070026

Reference yield: 77.0%

2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-ethylimidazole (902138-01-6) + zinc(II) chloride (7646-85-7,24359-56-6) → bis(2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-ethylimidazole)dichlorozinc

Guidance literature:

In acetone; org. ligand and ZnCl2 mixed in anhyd. acetone (20-25°C); kept (8 h); pptd. with hexane; filtered; washed with acetone-hexane mixt. (1:1); dried (vac.); elem. anal.;

DOI:10.1134/S1070328408070026

upstream raw materials:

1-ethyl-2-formylimidazole

Refernces