Mo₂(DPhIP)4

Base Information

• Chemical Name: Mo₂(DPhIP)4
• CAS No.: 265114-82-7
• Molecular Formula: C₆₈H₆₄Mo₂N₁₂
• Molecular Weight: 1241.22
• Mol file: 265114-82-7.mol

Synonyms:

Chemical Property of Mo₂(DPhIP)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mo₂(DPhIP)4

There total 2 articles about Mo₂(DPhIP)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

2,6-di(phenylimino)piperidine (101878-69-7) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → Mo2(DPhIP)4 (265114-82-7)

Guidance literature:

In hexane; Mo(CO)6 and H(DPhIP) in o-dichlorobenzene-hexane mixt. were heated overnight to 80°C and then to reflux temp. for 24 h; react. mixt. was concd. and mixed with Et2O, product was collected by filtration, washed with acetone and ethanol, and dried under vac. overnight; elem. anal.;

DOI:10.1021/ic991274u

Reference yield:

dimolybdenum acetate (14221-06-8,744215-74-5) + 2,6-di(phenylimino)piperidine (101878-69-7) → Mo2(DPhIP)2(O2CCH3)2 + Mo2(DPhIP)4 (265114-82-7)

Guidance literature:

With methyllithium; In tetrahydrofuran; under N2 atm. H(DPhIP) was dissolved in THF and deprotonated at -78°C by methyllithium in THF, this soln. was added to Mo2(O2CCH3)4 and react. mixt. was heated at reflux temperature overnight; soln. was filtered and layered with hexane; elem. anal.;

DOI:10.1021/ic991274u

Reference yield: 84.0%

Mo2(DPhIP)4 (265114-82-7) + copper(l) chloride → [Mo2Cu2(DPhIP)4](CuCl2)2

Guidance literature:

In dichloromethane; under N2 atm. Mo2(DPhIP)4 was dissolved in CH2Cl2 and added to suspension CuCl in CH2Cl2, mixt. was heated at reflux temp. for 1 h; product was collected by filtration, washed with CH2Cl2 and dried undervac.; elem. anal.;

DOI:10.1021/ic991274u

upstream raw materials:

2,6-di(phenylimino)piperidine

molybdenum hexacarbonyl

dimolybdenum acetate