Ph₃PMe[PhCCAuCCPh]

Base Information

• Chemical Name: Ph₃PMe[PhCCAuCCPh]
• CAS No.: 908863-40-1
• Molecular Formula: C₁₆H₁₀Au*C₁₉H₁₈P
• Molecular Weight: 676.548
• Mol file: 908863-40-1.mol

Synonyms:

Chemical Property of Ph₃PMe[PhCCAuCCPh]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ph₃PMe[PhCCAuCCPh]

There total 2 articles about Ph₃PMe[PhCCAuCCPh] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + lithium phenylacetylide (4440-01-1) + methyl iodide (74-88-4) → Ph3PMe[PhCCAuCCPh] (908863-40-1)

Guidance literature:

In diethyl ether; byproducts: cis-Me2(PhCC)AuPPh3; (N2); addn. of soln. of PhCCLi in ether to suspn. of gold compd. in ether with stirring at 25.degree, cooling to -75°C, addn. of MeI, warming to room temp., stirring for 2 h; evapn., extn. (water), dissolving in CH2Cl2, filtration through dry MgSO4, addn. of pentane, elem. anal.;

DOI:10.1016/j.ica.2006.01.041

Reference yield:

methyl(triphenylphosphine)gold(I) → Ph3PMe[PhCCAuCCPh] (908863-40-1)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether

2: diethyl ether

In diethyl ether;

DOI:10.1016/j.ica.2006.01.041

upstream raw materials:

(triphenylphosphine)gold(I) chloride

lithium phenylacetylide

methyl iodide