[Pd(O₂CCF₂CF₃-O)2(1,1'-bis(diphenylphosphino)ferrocene)]

Base Information

• Chemical Name: [Pd(O₂CCF₂CF₃-O)2(1,1'-bis(diphenylphosphino)ferrocene)]
• CAS No.: 423124-23-6
• Molecular Formula: C₄₀H₂₈F₁₀FeO₄P₂Pd
• Molecular Weight: 986.858
• Mol file: 423124-23-6.mol

Synonyms:

Chemical Property of [Pd(O₂CCF₂CF₃-O)2(1,1'-bis(diphenylphosphino)ferrocene)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [Pd(O₂CCF₂CF₃-O)2(1,1'-bis(diphenylphosphino)ferrocene)]

There total 1 articles about [Pd(O₂CCF₂CF₃-O)2(1,1'-bis(diphenylphosphino)ferrocene)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride (72287-26-4,95464-05-4) + silver(I) pentafluoropropionate (509-09-1) → [Pd(O2CCF2CF3-O)2(1,1'-bis(diphenylphosphino)ferrocene)] (423124-23-6)

Guidance literature:

In dichloromethane; under Ar, standard Schlenk techniques; soln. of Pd complex and Ag compd.(2 equiv.) in CH2Cl2 shielded from direct light was stirred at room tem p. for ca. 20 h; filtered through column Celite; filtrate concd.; crystn. after addn. of hexane; elem. anal.;

DOI:10.1039/b104539n

Reference yield: 88.0%

[Pd(O2CCF2CF3-O)2(1,1'-bis(diphenylphosphino)ferrocene)] (423124-23-6) + water (7732-18-5) + silver(I) pentafluoropropionate (509-09-1) → [PdAg(μ-O2CCF2CF3)2(O2CCF2CF3-O)(1,1'-bis(diphenylphosphino)ferrocene)]

Guidance literature:

In dichloromethane; under Ar, standard Schlenk techniques; Ag compd. was added to soln. of Pd complex in CH2Cl2; mixt. was stirred for 30 min, shielded from direct light; filtered; filtrate was slowly diffused through a layer of hexane with shielding from direct light; crystals collected; elem. anal.;

DOI:10.1039/b104539n

upstream raw materials:

(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride

silver(I) pentafluoropropionate

Refernces