[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

Base Information

• Chemical Name: [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
• CAS No.: 72287-26-4
• Molecular Formula: C34H28Cl2FeP2Pd
• Molecular Weight: 851.095
• Hs Code.: 28439000
• Mol file: 72287-26-4.mol

Synonyms:Palladium,[1,1'-bis(diphenylphosphino)ferrocene-P,P']dichloro-, (SP-4-2)-;Ferrocene,1,1'-bis(diphenylphosphino)-, palladium complex;(Bis(h5-(diphenylphosphino)cyclopentadienyl)iron)dichloropalladium;1,1'-Bis(diphenylphosphino)ferrocenedichloropalladium(II);1,1'-Bis(diphenylphosphino)ferrocenepalladium dichloride;Dichloro(diphenylphosphinoferrocene)palladium;Dichloro[1,1'-bis(diphenylphosphine)ferrocene]palladium(II);Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium;Pd(dppf)Cl2;PdCl2(dppf);[1,1'-Bis(diphenylphosphino-kP)ferrocene]dichloropalladium;

Chemical Property of [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

Chemical Property:

• Melting Point: 275-280 °C(lit.)
• PSA: 27.18000
• LogP: 7.76790
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Solubility.: Soluble in dichloromethane.

Purity/Quality:

99% ^*data from raw suppliers

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn, Xi
• Hazard Codes: Xn,Xi
• Statements: 20/21/22-36/37/38-40
• Safety Statements: 23-24/25-26-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Uses: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds. Is used in preparation of Nucleosides as Ectonucleotidase inhibitors. [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings. Catalyst for C-C and C-N coupling reaction. suzuki reaction

Technology Process of [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

There total 27 articles about [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.7%

hydrogenchloride (7647-01-0,15364-23-5) + 1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + palladium (7440-05-3) → (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride (72287-26-4,95464-05-4)

Guidance literature:

In tetrahydrofuran; ethanol; water; at 55 - 60 ℃; for 3h; Solvent; Temperature; Inert atmosphere;

Reference yield: 99.0%

1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) → (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride (72287-26-4,95464-05-4)

Guidance literature:

In benzene; (Ar); addn. of soln. of Pd(PhCN)2Cl2 in benzene to soln. of Fe(C5H4PPh2)2 in benzene; pptn. for a few minutes; stirring overnight; crystn., filtration, washing with benzene, drying under vac.;

DOI:10.1021/om050869w

Reference yield: 98.0%

Methyl methanesulfonate (66-27-3) + Pd(η2-CH2=CHCHO)(dppf) (590420-33-0) → (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride (72287-26-4,95464-05-4) + [(η3-CH2CHCH(OCH3))Pd(dppf)][CH3SO3] (646068-10-2,646068-71-5)

Guidance literature:

In further solvent(s); under N2 atm. to soln. Pd(CH2=CHCHO)(dppf) in C2D4Cl2 MeOMs was added atroom temp. and heated to 60°C; identified by NMR;

DOI:10.1021/om034122m

upstream raw materials:

1,1'-bis-(diphenylphosphino)ferrocene

diamminedichloropalladium(II)

{1,1'-bis(diphenylphosphino)ferrocene} palladium dibromide

dichloromethane

Downstream raw materials:

N₁-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-phenylbenzene]-1-benzenesulfonamide

1-(phenylsulfonyl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)indoline

N₁-[2-chloro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-N₁-methyl-1-benzenesulfonamide

methyl 3-[(2R)-2-({(tert-butoxycarbonyl)[(2R)-2-{[tert-butyl(dimethyl)silyl]oxy}-2-(3-pyridinyl)ethyl]amino}methyl)-3,4-dihydro-2H-chromen-6-yl]benzoate

Refernces

• 1、 Kunkely, Horst,Vogler, Arnd. "Photo-oxidation of bis[1,2-bis(diphenylphosphino)ferrocene]-palladium(0) in CCl4 induced by ferrocene to solvent charge transfer excitation". . p. 215 - 217. Retrieved 1998.
• 2、 Housecroft, Catherine E.,Owen, Steven M.,Raithby, Paul R.,Shaykh, Bilal A. M.. "Preparation, molecular structure, and solution properties of 1-[1,1′-bis(diphenylphosphino)ferrocene]palladatetraborane". . p. 1617 - 1623. Retrieved 1990.
• 3、 -. "Preparation method of [1, 1'-bis (diphenylphosphino) ferrocene] palladium dichloride". Paragraph 0030-0048. . Retrieved 2021/02/06.