(1,1'-di(triphenylmethyl)-4,4'-biimidazole)PdMe₂

Base Information

Chemical Name:(1,1'-di(triphenylmethyl)-4,4'-biimidazole)PdMe₂
CAS No.:1005000-31-6
Molecular Formula:C₄₆H₄₀N₄Pd
Molecular Weight:755.27
Hs Code.:

(1,1'-di(triphenylmethyl)-4,4'-biimidazole)PdMe<sub>2</sub>

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Chemical Property of (1,1'-di(triphenylmethyl)-4,4'-biimidazole)PdMe₂

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Technology Process of (1,1'-di(triphenylmethyl)-4,4'-biimidazole)PdMe₂

There total 1 articles about (1,1'-di(triphenylmethyl)-4,4'-biimidazole)PdMe₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: dimethyl(pyridazine)palladium(II)

: 1,1'-bis(triphenylmethyl)-4,4'-biimidazole

: 1005000-31-6
(1,1'-di(triphenylmethyl)-4,4'-biimidazole)PdMe₂

Guidance literature:: In dichloromethane; under N2, in the dark; CH2Cl2 added to mixt. of Pd complex and ligand; stirred at 23°C for 5 min; poured into pentane; filtered; ppt. rinsed with acetone, Et2O and pentane; dried under vac.;
DOI:10.1021/om700767r

Reference yield:

: 1005000-31-6
(1,1'-di(triphenylmethyl)-4,4'-biimidazole)PdMe₂

: N,N'-dimethylaniliniumtetrakis(pentafluorophenyl)borate

: 1005000-39-4
[(1,1'-di(triphenylmethyl)-4,4'-biimidazole)PdMe(NMe₂Ph)][B(C₆F₅)4]

Guidance literature:: In dichloromethane-d2; byproducts: CH4; under N2; in NMR tube; CD2Cl2 added at -78°C to mixt. of Pd complex and (HNMe2Ph)B(C6F5)4; shaken at -78°C; not isolated; detd. by (1)H and (13)C NMR spectra;
DOI:10.1021/om700767r

Reference yield:

: 74-85-1
ethene

: 1005000-31-6
(1,1'-di(triphenylmethyl)-4,4'-biimidazole)PdMe₂

: N,N'-dimethylaniliniumtetrakis(pentafluorophenyl)borate

: 1005000-68-9
[(1,1'-di(triphenylmethyl)-4,4'-biimidazole)PdMe(ethylene)][B(C₆F₅)4]

Guidance literature:: In dichloromethane-d2; byproducts: CH4; under N2; in NMR tube; Pd complex and (HNMe2Ph)B(C6F5)4 reacted in CD2Cl2 at -78°C; cooled to -196°C; exposed to ethylene (ca. 10 equiv.); sealed; warmed to -78°C; not isolated; detd. by (1)H and (13)C NMR spectra;
DOI:10.1021/om700767r