[Pd(I)2Br₂(2,6-Me₂C₆H₃NC)4]

Base Information

Chemical Name:[Pd(I)2Br₂(2,6-Me₂C₆H₃NC)4]
CAS No.:185812-87-7
Molecular Formula:C₃₆H₃₆Br₂N₄Pd₂
Molecular Weight:897.357
Hs Code.:

[Pd(I)2Br<sub>2</sub>(2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>NC)4]

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Chemical Property of [Pd(I)2Br₂(2,6-Me₂C₆H₃NC)4]

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Technology Process of [Pd(I)2Br₂(2,6-Me₂C₆H₃NC)4]

There total 4 articles about [Pd(I)2Br₂(2,6-Me₂C₆H₃NC)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 185812-86-6
di-μ-bromobis-(tritert-butylphosphine)dipalladium(I)

: 119072-54-7,2769-71-3
2,6-dimethylphenyl isonitrile

: 185812-87-7
Pd₂Br₂(2,6-dimethylphenylisocyanide)4

Guidance literature:: In acetone; toluene; under N2; acetone soln. of 4 equiv. isonitril was added to toluene soln. of Pd-complex, stirring for 2 h; hexane was added, solid was pptd., elem. anal.;
DOI:10.1016/S0022-328X(00)00187-X

Reference yield: 71.0%

: Pd2(dba)4

: 119072-54-7,2769-71-3
2,6-dimethylphenyl isonitrile

: 6630-33-7
ortho-bromobenzaldehyde

: 185812-87-7
[Pd(I)2Br₂(2,6-Me₂C₆H₃NC)4]

Guidance literature:: In toluene; addn. of o-bromobenzaldehyde under N2 to suspn. of Pd2(dibenzylideneacetone)3*dibenzylideneacetone (1 equiv.) and Me2C6H3NC (4 equiv.) in toluene, reflux for 5 h, stirring at room temp. for 16 h; evapn. of solvent in air, extn. with CH2Cl2, filtration of extract over anhyd. MgSO4, evapn., trituration with Et2O, pptn., filtration, washing with Et2O, drying in air;
DOI:10.1021/om020380s

Reference yield:

: 119072-54-7,2769-71-3
2,6-dimethylphenyl isonitrile

: 459820-54-3
[Pd(C(NC₆H₃(CH₃)2-2,6)C₆H₄CH₂NH₂-2)Br(2,6-Me₂C₆H₃NC)2]

: 185812-87-7
[Pd(I)2Br₂(2,6-Me₂C₆H₃NC)4]

Guidance literature:: Multi-step reaction with 2 steps

1: dichloromethane

2: chloroform-d1

In chloroform-d1; dichloromethane;
DOI:10.1021/om020365n