C₂₅H₁₃O₅PW

Base Information

• Chemical Name: C₂₅H₁₃O₅PW
• CAS No.: 1446498-28-7
• Molecular Formula: C₂₅H₁₃O₅PW
• Molecular Weight: 608.199
• Mol file: 1446498-28-7.mol

Synonyms:

Chemical Property of C₂₅H₁₃O₅PW

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₅H₁₃O₅PW

There total 5 articles about C₂₅H₁₃O₅PW which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C29H24O9P2W (1446498-22-1) → C25H13O5PW (1446498-28-7)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; n-heptane; ethylbenzene; at -78 - 20 ℃;

DOI:10.1002/anie.201301469

Reference yield:

(O,O-diethyl)phosphonatophenylphosphine tungsten pentacarbonyl (116972-70-4) + 9H-fluorene-9-carbonyl chloride (24168-51-2) → C25H13O5PW (1446498-28-7)

Guidance literature:

(O,O-diethyl)phosphonatophenylphosphine tungsten pentacarbonyl; With lithium tert-butoxide; In tetrahydrofuran; at -78 ℃; for 0.0833333h; Inert atmosphere; Schlenk technique;

9H-fluorene-9-carbonyl chloride; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201301469

Reference yield:

(O,O-diethyl)phosphonatophenylphosphine tungsten pentacarbonyl (116972-70-4) + fluoren-9-ylidene-methanone (40012-77-9) → C25H13O5PW (1446498-28-7)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 20 ℃; for 120h; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201301469

upstream raw materials:

9H-fluorene-9-carboxylic acid

9H-fluorene-9-carbonyl chloride

(O,O-diethyl)phosphonatophenylphosphine tungsten pentacarbonyl

fluoren-9-ylidene-methanone