[Rh(O₂CCF₃)(HC₂C₆H₅)(P(CH(CH₃)2)3)2]

Base Information

Chemical Name:[Rh(O₂CCF₃)(HC₂C₆H₅)(P(CH(CH₃)2)3)2]
CAS No.:161271-69-8
Molecular Formula:C₂₈H₄₈F₃O₂P₂Rh
Molecular Weight:638.536
Hs Code.:

[Rh(O<sub>2</sub>CCF<sub>3</sub>)(HC<sub>2</sub>C<sub>6</sub>H<sub>5</sub>)(P(CH(CH<sub>3</sub>)2)3)2]

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Chemical Property of [Rh(O₂CCF₃)(HC₂C₆H₅)(P(CH(CH₃)2)3)2]

Chemical Property:

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Technology Process of [Rh(O₂CCF₃)(HC₂C₆H₅)(P(CH(CH₃)2)3)2]

There total 1 articles about [Rh(O₂CCF₃)(HC₂C₆H₅)(P(CH(CH₃)2)3)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 137854-77-4
{rhodium(η2-trifluoracetato)(triisopropylphosphine)2}

: 536-74-3
phenylacetylene

: 161271-69-8
[Rh(O₂CCF₃)(HC₂C₆H₅)(P(CH(CH₃)2)3)2]

Guidance literature:: In pentane; Ar; org. compd. addn. dropwise to Rh-compd. soln. at 0°C, soln. evapn. (vac.) until crystn. began, further crystn. on cooling to -78°C; solid filtration off, washing (pentane), vac. drying; elem. anal.;
DOI:10.1016/0022-328X(94)24750-D

Reference yield: 86.0%

: 161271-69-8
[Rh(O₂CCF₃)(HC₂C₆H₅)(P(CH(CH₃)2)3)2]

: trans-[Rh(CF₃CO₂)(=C=CHPh)(PiPr₃)2]

Guidance literature:: In benzene; Ar; stirring Rh-compd. soln. at room temp. for 2 h, solvent suction off, residue dissoln. (pentane), crystn. on cooling to -78°C; crystals filtration off, washing (pentane), vac. drying; elem. anal.;
DOI:10.1016/0022-328X(94)24750-D

Reference yield: 85.0%

: 110-86-1
pyridine

: 161271-69-8
[Rh(O₂CCF₃)(HC₂C₆H₅)(P(CH(CH₃)2)3)2]

: [Rh(H)(O₂CCF₃)(CCHC₆H₅)(C₅H₅N)(P(CH(CH₃)2)3)2]

Guidance literature:: In pentane; Ar; org. ligand addn. to Rh-compd. soln., mixt. stirring at room temp. for 30 min, volatile components removal (vac.), oily residue dissoln., pptn. on cooling to -78°C; ppt. washing (pentane), vac. drying; elem. anal.;
DOI:10.1016/0022-328X(94)24750-D