Technology Process of C28H48O7SSi
There total 17 articles about C28H48O7SSi which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C28H50O7SSi;
With
oxalyl dichloride; dimethyl sulfoxide;
In
dichloromethane;
at -78 ℃;
for 0.75h;
With
triethylamine;
In
dichloromethane;
for 0.166667h;
DOI:10.1002/anie.201203935
- Guidance literature:
-
Multi-step reaction with 10 steps
1.1: 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride / toluene / 2.25 h / 95 °C
2.1: lithium aluminium tetrahydride / diethyl ether / 0.5 h / 0 °C
3.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.75 h / -78 °C
3.2: 0.17 h
4.1: tert.-butyl lithium / diethyl ether; pentane / 0.58 h / -78 - 20 °C
4.2: 0.5 h / -78 °C
5.1: pyridinium p-toluenesulfonate / dichloromethane / 14 h
6.1: palladium 10% on activated carbon; hydrogen / isopropyl alcohol / 18 h
7.1: tributylphosphine / tetrahydrofuran / 15 h / 0 - 20 °C
8.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / acetonitrile / 12 h / 20 °C
9.1: pyridine hydrogenfluoride / tetrahydrofuran / 24 h / 0 °C
10.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.75 h / -78 °C
10.2: 0.17 h
With
lithium aluminium tetrahydride; tetrapropylammonium perruthennate; oxalyl dichloride; 2,2'-azobis(isobutyronitrile); tributylphosphine; palladium 10% on activated carbon; hydrogen; tert.-butyl lithium; tri-n-butyl-tin hydride; pyridinium p-toluenesulfonate; pyridine hydrogenfluoride; dimethyl sulfoxide; 4-methylmorpholine N-oxide;
In
tetrahydrofuran; diethyl ether; dichloromethane; isopropyl alcohol; toluene; acetonitrile; pentane;
DOI:10.1002/anie.201203935
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: palladium 10% on activated carbon; hydrogen / isopropyl alcohol / 18 h
2.1: tributylphosphine / tetrahydrofuran / 15 h / 0 - 20 °C
3.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / acetonitrile / 12 h / 20 °C
4.1: pyridine hydrogenfluoride / tetrahydrofuran / 24 h / 0 °C
5.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.75 h / -78 °C
5.2: 0.17 h
With
tetrapropylammonium perruthennate; oxalyl dichloride; tributylphosphine; palladium 10% on activated carbon; hydrogen; pyridine hydrogenfluoride; dimethyl sulfoxide; 4-methylmorpholine N-oxide;
In
tetrahydrofuran; dichloromethane; isopropyl alcohol; acetonitrile;
DOI:10.1002/anie.201203935
