fac-[Mn(CO)3(2,2'-bipyridyl)((phenylthio)methyl)]

Base Information

Chemical Name:fac-[Mn(CO)3(2,2'-bipyridyl)((phenylthio)methyl)]
CAS No.:478971-18-5
Molecular Formula:C₂₀H₁₅MnN₂O₃S
Molecular Weight:418.355
Hs Code.:

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Chemical Property of fac-[Mn(CO)3(2,2'-bipyridyl)((phenylthio)methyl)]

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Technology Process of fac-[Mn(CO)3(2,2'-bipyridyl)((phenylthio)methyl)]

There total 2 articles about fac-[Mn(CO)3(2,2'-bipyridyl)((phenylthio)methyl)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 7205-91-6
phenylthiomethyl chloride

: 38173-71-6
{MnBr(2,2'-bipyridyl)(CO₃)3}

: 478971-18-5
fac-[Mn(CO)3(2,2'-bipyridyl)((phenylthio)methyl)]

Guidance literature:: With sodium amalgame; In tetrahydrofuran; under N2, Schlenk techniques; THF added to MnBr(CO)3(C10H8N2); mixt. stirred to complete dissolution; Na/Hg added; stirred for 2 h at room temp.; monitored by IR; soln. transferred onto soln. ClCH2SPh in THF precooled to -78°C; filtered through Florisil; solvent removed under vac.; hexane slowly diffused into soln. at room temp.; elem. anal.;
DOI:10.1021/om020522i

Reference yield:

: 478971-26-5
fac-[Mn(CO)3(2,2'-bipyridyl)(CH₂S(CH₃)(C₆H₅))]CF₃SO₃

: 478971-18-5
fac-[Mn(CO)3(2,2'-bipyridyl)((phenylthio)methyl)]

Guidance literature:: With potassium diphenylphosphide; In tetrahydrofuran; byproducts: CH3P(C6H5)2; to soln. of metal complex in THF cooled to -78°C was added a soln. of KPPh2 in THF; mixt. stirred for 20 min; volatiles removed undr vac.; residue extd. with CH2Cl2; solvent evapd.; redissolved in THF; hexane slowly diffused into this soln. at room temp.;
DOI:10.1021/om020522i

Reference yield: 94.0%

: 478971-18-5
fac-[Mn(CO)3(2,2'-bipyridyl)((phenylthio)methyl)]

: 333-27-7
methyl trifluoromethanesulfonate

: 478971-26-5
fac-[Mn(CO)3(2,2'-bipyridyl)(CH₂S(CH₃)(C₆H₅))]CF₃SO₃

Guidance literature:: In dichloromethane; methyl triflate added to soln. of metal complex in CH2Cl2 at -78°C; allowed to reach room temp.; stirred for 15 min; solvent removed under vac.; hexane diffused into THF soln. at room temp.; elem. anal.;
DOI:10.1021/om020522i