{(C₆H₅)4P}{Cu(bis(trifluoromethyl)ethylenediselenolato)2}

Base Information

• Chemical Name: {(C₆H₅)4P}{Cu(bis(trifluoromethyl)ethylenediselenolato)2}
• CAS No.: 113352-38-8
• Molecular Formula: C₈CuF₁₂Se₄*C₂₄H₂₀P
• Molecular Weight: 1042.85
• Mol file: 113352-38-8.mol

Synonyms:

Chemical Property of {(C₆H₅)4P}{Cu(bis(trifluoromethyl)ethylenediselenolato)2}

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of {(C₆H₅)4P}{Cu(bis(trifluoromethyl)ethylenediselenolato)2}

There total 1 articles about {(C₆H₅)4P}{Cu(bis(trifluoromethyl)ethylenediselenolato)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

cis-bis(trifluoromethyl)diselenete (17744-01-3) + tetrameric (triphenylphosphine)copper(I) iodide (47107-74-4) + tetraphenylphosphonium bromide (2751-90-8) → {(C6H5)4P}{Cu(bis(trifluoromethyl)ethylenediselenolato)2} (113352-38-8)

Guidance literature:

In benzene; Addn. of soln. of (CF3)2C2Se2 in C6H6 to a suspn. of (Ph3P)CuI in C6H6. The mixt. was stirred (4 h). It was then taken to dryness and resuspended in aq. EtOH. The soln. was filtered, extd. (n-pentane) and decanted into a soln. of {PPh4}Br in aq. EtOH.; The mixt. was allowed to slowly evap., and the deposited solids were collected and recrystd. from hot aq. 2-propanol. Elem.anal.;

upstream raw materials:

cis-bis(trifluoromethyl)diselenete

tetrameric (triphenylphosphine)copper(I) iodide

tetraphenylphosphonium bromide