CID 12549340

Base Information

• Chemical Name: CID 12549340
• CAS No.: 47107-74-4
• Molecular Formula: C18H15CuIP
• Molecular Weight: 452.741
• Mol file: 47107-74-4.mol

Synonyms:SCHEMBL6937168

Chemical Property of CID 12549340

Chemical Property:

• Vapor Pressure: 4.74E-05mmHg at 25°C
• Boiling Point: 360°Cat760mmHg
• Flash Point: 181.7°C
• PSA: 13.59000
• Density: g/cm³
• LogP: 0.44630
• Water Solubility.: 730μg/L at 20.9℃
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 451.92521
• Heavy Atom Count: 21
• Complexity: 204

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cu]I

Technology Process of CID 12549340

There total 8 articles about CID 12549340 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

copper(l) iodide (7681-65-4) + triphenylphosphine (603-35-0) → tetrameric (triphenylphosphine)copper(I) iodide (47107-74-4)

Guidance literature:

In acetonitrile; (N2); addn. of soln. of PPh3 in MeCN to soln. of CuI in the same solvent; pptn., stirring for 1 h; filtration, washing with MeCN, drying in vac., elem. anal.;

DOI:10.1021/om020896b

Reference yield: 90.0%

[Cu(C*CPh)(PPh3)]4 + trans-Pt(I)(C6H4F-p)(PEt3)2 (136983-12-5,14245-00-2) → tetrakis-[iodotriphenylphosphinecopper(I)] (47107-74-4) + trans-Pt(C*CPh)(C6H4F)(PEt3)2 (60498-01-3,15670-84-5)

Guidance literature:

N2 or Ar-atmosphere; Cu:Pt 1:1 ratio; elem. anal.;

DOI:10.1021/om970266n

Reference yield: 84.0%

copper(l) iodide (7681-65-4) + triphenylphosphine (603-35-0) → tetrakis-[iodotriphenylphosphinecopper(I)] (47107-74-4)

Guidance literature:

In chloroform; for 1h; Reflux;

DOI:10.1002/adsc.201300126

upstream raw materials:

bis(η-cyclopentadienyl)(μ-carbonyl)(μ-bis(diphenylphosphino)methane)(μ-copperchloride)dirhodium

copper(l) iodide

triphenylphosphine

N-phenyl-2-(thiophen-2-ylmethylene)-hydrazinecarbothioamide

Downstream raw materials:

Cu(P(C₆H₅)3)2⁽¹⁺⁾*PF₆^(1-)=[Cu(P(C₆H₅)3)2]PF₆

thallium chloride

N,N,N,N-tetraethylammonium tetrafluoroborate

{(C₆H₅)4P}{Cu(bis(trifluoromethyl)ethylenediselenolato)2}