Technology Process of C15H18O5
There total 5 articles about C15H18O5 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium hydroxide;
In
tetrahydrofuran; water;
at 20 ℃;
for 11h;
optical yield given as %de;
diastereoselective reaction;
DOI:10.1016/j.tetlet.2011.01.078
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: dihydrogen peroxide; sodium hydroxide / methanol; water / 0.02 h / 0 °C
2.1: diisobutylaluminium hydride / toluene / 1 h / -78 °C
2.2: 1 h / -40 °C
3.1: potassium hydroxide / tetrahydrofuran; water / 11 h / 20 °C
With
dihydrogen peroxide; diisobutylaluminium hydride; potassium hydroxide; sodium hydroxide;
In
tetrahydrofuran; methanol; water; toluene;
2.2: Horner-Wadsworth-Emmons olefination / 3.1: intramolecular oxy-Michael reaction;
DOI:10.1016/j.tetlet.2011.01.078
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 6 h / Reflux
2.1: dihydrogen peroxide; sodium hydroxide / methanol; water / 0.02 h / 0 °C
3.1: diisobutylaluminium hydride / toluene / 1 h / -78 °C
3.2: 1 h / -40 °C
4.1: potassium hydroxide / tetrahydrofuran; water / 11 h / 20 °C
With
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; dihydrogen peroxide; diisobutylaluminium hydride; potassium hydroxide; sodium hydroxide;
In
tetrahydrofuran; methanol; dichloromethane; water; toluene;
3.2: Horner-Wadsworth-Emmons olefination / 4.1: intramolecular oxy-Michael reaction;
DOI:10.1016/j.tetlet.2011.01.078
