640298-47-1

Upstream product

• 58931-16-1 (R)-1-benzyloxypent-4-en-2-ol 
• 814-68-6 acryloyl chloride 
• 3536-96-7 vinylmagnesium chloride 
• 14618-80-5 (R)-benzyl glycidol 

Downstream Products

• 1280213-76-4 C₁₇H₂₂O₅ 
• 1280213-77-5 C₁₅H₁₈O₅ 
• 1280213-78-6 C₁₇H₂₂O₅ 
• 1280213-79-7 C₁₅H₁₈O₅ 
• 1280213-80-0 C₁₅H₂₀O₄ 
• 1280213-93-5 C₂₁H₃₄O₄Si 
• 1280213-82-2 C₃₆H₅₆O₄Si₂ 
• 130194-53-5 (1S,4R,6S)-4-Benzyloxymethyl-3,7-dioxa-bicyclo[4.1.0]heptan-2-one 
• 122046-63-3 (6R)-6-[(2S,3S)-3-phenyloxiran-2-yl]-5,6-dihydro-2H-pyran-2-one 
• 22639-28-7 (R)-goniothalamin 
• 120996-46-5 (R)-6-Benzyloxymethyl-5,6-dihydro-2-pyrone 

Relevant academic research and scientific papers

Total synthesis of (+)-aspergillide C

The enantioselective total synthesis of aspergillide C, a member of a novel class of 14-membered macrolides isolated from the marine-derived fungus Aspergillus ostianus strain 01F313, has been accomplished employing a highly diastereoselective intramolecu

Total synthesis of (R)-(+)-goniothalamin and (R)-(+)-goniothalamin oxide: first application of the sulfoxide-modified Julia olefination in total synthesis

A short and efficient synthesis of (R)-(+)-goniothalamin 1 and (R)-(+)-goniothalamin oxide 2 is described. During this approach, the sulfoxide-modified Julia olefination was used as a key step to connect aldehyde 5 to sulfoxide 6. The desired styryl-containing adduct is obtained in good yield and with excellent E/Z selectivity.