trans-[Cl(PMe3)2Pt(μ-BN(SiMe3)2C=C)Ph]

Base Information

• Chemical Name: trans-[Cl(PMe3)2Pt(μ-BN(SiMe3)2C=C)Ph]
• CAS No.: 1203465-35-3
• Molecular Formula: C₂₀H₄₁BClNP₂PtSi₂
• Molecular Weight: 655.015
• Mol file: 1203465-35-3.mol

Synonyms:

Chemical Property of trans-[Cl(PMe3)2Pt(μ-BN(SiMe3)2C=C)Ph]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[Cl(PMe3)2Pt(μ-BN(SiMe3)2C=C)Ph]

There total 1 articles about trans-[Cl(PMe3)2Pt(μ-BN(SiMe3)2C=C)Ph] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

[(OC)5Cr=B=N(SiMe3)2] + [PtCl(P(CH3)3)2(CCC6H5)] (816419-05-3) → trans-[Cl(PMe3)2Pt(μ-BN(SiMe3)2C=C)Ph] (1203465-35-3)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); soln. of Cr- and Pt-complexes in THF photolyzed at room temp. under dry Ar for 7 h; filtered; crystd. from hexane at -60°C;

DOI:10.1039/b915926f

Reference yield: 65.0%

trans-[Cl(PMe3)2Pt(μ-BN(SiMe3)2C=C)Ph] (1203465-35-3) → trans-[Cl(PMe3)2PtBN(SiMe3)2C.ident.C)Ph]

Guidance literature:

In benzene-d6; Irradiation (UV/VIS); (Ar); soln. of platinum complex in C6D6 was irradiated (Hg/Xe lamp (400-550 W) at 210-600 nm) for 4 h at room temp.; evapd. in vac., extd. with hexane, concd., crystd. at -30°C, elem. anal.;

DOI:10.1039/c0dt01694b

Reference yield: 38.0%

hydrogenchloride (7647-01-0,15364-23-5) + trans-[Cl(PMe3)2Pt(μ-BN(SiMe3)2C=C)Ph] (1203465-35-3) → trans-[Cl(PMe3)2PtCH=C(BClN(SiMe3)2Ph] (1291072-35-9)

Guidance literature:

In toluene; benzene; (Ar); soln. of platinum complex in toluene was treated at -70°C with benzene soln. of HCl, warmed to ambient temp.; filtered, filtrate was evapd., extd. with hexane, standed at room temp. for 1 h, filtered, crystd. at -30°C overnight, elem. anal.;

DOI:10.1039/c0dt01694b

upstream raw materials:

[PtCl(P(CH₃)3)2(CCC₆H₅)]

Downstream raw materials:

trans-[Br(PMe3)2Pt(μ-BN(SiMe3)2C=C)Ph]

trans-[Cl(PMe₃)2PtCH=C(BClN(SiMe₃)2Ph]