1291072-35-9Relevant academic research and scientific papers
Reactivity of a platinum-substituted borirene
Braunschweig, Holger,Ye, Qing,Radacki, Krzystof,Kupfer, Thomas
, p. 3666 - 3670 (2011/06/22)
We report on (i) the reactivity of the title compound trans-[Cl(PMe 3)2Pt{μ-BN(SiMe3)2C=C}Ph] (1), which underwent a photochemical rearrangement reaction to afford the platinum boryl complex trans-[Cl(PMe3)2PtBN(SiMe3) 2C≡CPh] (2), (ii) a ring-opening reaction by chemoselective boron-carbon bond cleavage resulting in the amino(vinyl)borane trans-[Cl(PMe3)2PtCH=C(BClN-(SiMe3) 2)Ph] (3), and (iii) a Cl-Br ligand exchange on the platinum atom yielding the Br-derivate trans-[Br(PMe3)2Pt{μ- BN(SiMe3)2C=C}Ph] (4). All compounds were fully characterized by multinuclear NMR spectroscopy and single crystal X-ray diffraction analysis. The Royal Society of Chemistry 2011.
