7,8,9,10,11-pentamethyl-1-phenyl-12-(trifluormethylsulfonyl)aza-closo-dodecaborane

Base Information

Chemical Name:7,8,9,10,11-pentamethyl-1-phenyl-12-(trifluormethylsulfonyl)aza-closo-dodecaborane
CAS No.:439276-64-9
Molecular Formula:C₁₂H₂₅B₁₁F₃NO₃S
Molecular Weight:439.318
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 7,8,9,10,11-pentamethyl-1-phenyl-12-(trifluormethylsulfonyl)aza-closo-dodecaborane

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Technology Process of 7,8,9,10,11-pentamethyl-1-phenyl-12-(trifluormethylsulfonyl)aza-closo-dodecaborane

There total 1 articles about 7,8,9,10,11-pentamethyl-1-phenyl-12-(trifluormethylsulfonyl)aza-closo-dodecaborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 174006-06-5
1-phenyl-1-aza-closo-dodecaborane⁽¹²⁾

: 1493-13-6
trifluorormethanesulfonic acid

: 333-27-7
methyl trifluoromethanesulfonate

: 439276-64-9
7,8,9,10,11-pentamethyl-1-phenyl-12-(trifluormethylsulfonyl)aza-closo-dodecaborane

Guidance literature:: In neat (no solvent); 140 °C for 20 h; excess of CF3SO3X (X=H and Me) was removed in vac., residue was extd. three times with hexane, hexane was removed, residue was sublimed (80 °C/0.001 mbar), recrystn. from hexane at -40 °C, elem. anal.;
DOI:10.1002/1521-3749(200203)628:3<632::AID-ZAAC632>3.0.CO;2-8

Reference yield: 99.0%

: 439276-64-9
7,8,9,10,11-pentamethyl-1-phenyl-12-(trifluormethylsulfonyl)aza-closo-dodecaborane

: 7732-18-5
water

: H⁽¹⁺⁾*C₆H₅NB₁₁H₅(CH₃)5O₃SCF₃(OH)^(1-)=H[C₆H₅NB₁₁(CH₃)5H₅(O₃SCF₃)(OH)]

Guidance literature:: In deuteromethanol; H2O was added in MeOD at 25 °C, stirring for 12 h; not isolated, detected by NMR;
DOI:10.1002/1521-3749(200203)628:3<632::AID-ZAAC632>3.0.CO;2-8