(4'R^*,5'R^*)-endo-6-<2-(benzyloxy)ethyl>-endo-2-(2',2'-dimethyl-5'-n-pentyl-1',3'-dioxolan-4'-yl)-exo-3-(trimethylsilyl)-1-aza-7-oxabicyclo<2.2.1>heptane

Base Information

• Chemical Name: (4'R^*,5'R^*)-endo-6-<2-(benzyloxy)ethyl>-endo-2-(2',2'-dimethyl-5'-n-pentyl-1',3'-dioxolan-4'-yl)-exo-3-(trimethylsilyl)-1-aza-7-oxabicyclo<2.2.1>heptane
• CAS No.: 116911-46-7
• Molecular Formula: C₂₇H₄₅NO₄Si
• Molecular Weight: 475.744

Synonyms:

Chemical Property of (4'R^*,5'R^*)-endo-6-<2-(benzyloxy)ethyl>-endo-2-(2',2'-dimethyl-5'-n-pentyl-1',3'-dioxolan-4'-yl)-exo-3-(trimethylsilyl)-1-aza-7-oxabicyclo<2.2.1>heptane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (4'R^*,5'R^*)-endo-6-<2-(benzyloxy)ethyl>-endo-2-(2',2'-dimethyl-5'-n-pentyl-1',3'-dioxolan-4'-yl)-exo-3-(trimethylsilyl)-1-aza-7-oxabicyclo<2.2.1>heptane

There total 5 articles about (4'R^*,5'R^*)-endo-6-<2-(benzyloxy)ethyl>-endo-2-(2',2'-dimethyl-5'-n-pentyl-1',3'-dioxolan-4'-yl)-exo-3-(trimethylsilyl)-1-aza-7-oxabicyclo<2.2.1>heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-Benzyloxypropanal (19790-60-4) → (4'R*,5'R*)-endo-6-<2-(benzyloxy)ethyl>-endo-2-(2',2'-dimethyl-5'-n-pentyl-1',3'-dioxolan-4'-yl)-exo-3-(trimethylsilyl)-1-aza-7-oxabicyclo<2.2.1>heptane (116911-46-7)

Guidance literature:

Multi-step reaction with 2 steps

1: CaCl₂ / CH₂Cl₂ / 14 h / -20 °C

2: CH₂Cl₂ / 2 h / Heating

With calcium chloride; In dichloromethane;

DOI:10.1021/jo00261a001

Reference yield:

ethylene glycol trans-1-(trimethylsilyl)-1-propane-3-boronate (113999-42-1) → (4'R*,5'R*)-endo-6-<2-(benzyloxy)ethyl>-endo-2-(2',2'-dimethyl-5'-n-pentyl-1',3'-dioxolan-4'-yl)-exo-3-(trimethylsilyl)-1-aza-7-oxabicyclo<2.2.1>heptane (116911-46-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 521 mg / CCl₄ / 25 h / Heating

2: CaCl₂ / CH₂Cl₂ / 14 h / -20 °C

3: CH₂Cl₂ / 2 h / Heating

With calcium chloride; In tetrachloromethane; dichloromethane;

DOI:10.1021/jo00261a001

Reference yield:

(4S,5R)-2,2-Dimethyl-5-pentyl-[1,3]dioxolane-4-carbaldehyde oxime (116911-42-3,116949-70-3) → (4'R*,5'R*)-endo-6-<2-(benzyloxy)ethyl>-endo-2-(2',2'-dimethyl-5'-n-pentyl-1',3'-dioxolan-4'-yl)-exo-3-(trimethylsilyl)-1-aza-7-oxabicyclo<2.2.1>heptane (116911-46-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 521 mg / CCl₄ / 25 h / Heating

2: CaCl₂ / CH₂Cl₂ / 14 h / -20 °C

3: CH₂Cl₂ / 2 h / Heating

With calcium chloride; In tetrachloromethane; dichloromethane;

DOI:10.1021/jo00261a001

upstream raw materials:

3-Benzyloxypropanal

ethylene glycol trans-1-(trimethylsilyl)-1-propane-3-boronate

(4S,5R)-2,2-Dimethyl-5-pentyl-[1,3]dioxolane-4-carbaldehyde oxime

(1R^*,2R^*,4'S^*,5'R^*)-N-<1-(2',2'-dimethyl-5'-n-pentyl-1',3'-dioxolan-4'-yl)-2-(trimethylsilyl)-3-butenyl>hydroxylamine

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 116911-46-7 (4'R^*,5'R^*)-endo-6-<2-(benzyloxy)ethyl>-endo-2-(2',2'-dimethyl-5'-n-pentyl-1',3'-dioxolan-4'-yl)-exo-3-(trimethylsilyl)-1-aza-7-oxabicyclo<2.2.1>heptane

Send

Send

Metric Ton KG G Pound L ML

Send

Send