trans-dichloro-((Me)(Ph₂)phosphine)(carbonyl)platinum(II)

Base Information

• Chemical Name: trans-dichloro-((Me)(Ph₂)phosphine)(carbonyl)platinum(II)
• CAS No.: 73347-19-0
• Molecular Formula: C₁₄H₁₃Cl₂OPPt
• Molecular Weight: 494.216
• Mol file: 73347-19-0.mol

Synonyms:

Chemical Property of trans-dichloro-((Me)(Ph₂)phosphine)(carbonyl)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-dichloro-((Me)(Ph₂)phosphine)(carbonyl)platinum(II)

There total 12 articles about trans-dichloro-((Me)(Ph₂)phosphine)(carbonyl)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + diphenyl(methyl)phosphine (1486-28-8) → cis-dichloro-((Me)(Ph2)phosphine)(carbonyl)platinum(II) (73347-19-0,69109-32-6)

Guidance literature:

With carbon monoxide; In chloroform; CO passed through suspn. (PtCl2(cod)) in chloroform, after 1 h, chloroform soln. PMePh2 added dropwise over 30 min and CO passage continued over 30 min; soln. concd., ether added; elem. anal.;

DOI:10.1021/ic50220a003

Reference yield:

trans-dichloro-((Me)(Ph2)phosphine)(carbonyl)platinum(II) (69109-32-6,73347-19-0) → cis-dichloro-((Me)(Ph2)phosphine)(carbonyl)platinum(II) (73347-19-0,69109-32-6)

Guidance literature:

trans-Pt complex in chloroform or benzene or toluene, standing from 1-3d at ambient temp., can be catalysed by free CO, phosphine or halide ions, can be accelerated by light or u.v. irradn.;

DOI:10.1039/DT9800001988

Reference yield:

trans-dichloro-((Ph3)phosphine)(carbonyl)platinum(II) (19618-78-1,73347-20-3,22585-09-7) → cis-dichloro-((Me)(Ph2)phosphine)(carbonyl)platinum(II) (73347-19-0,69109-32-6)

Guidance literature:

carbon monoxide; In not given; excess CO;

DOI:10.1016/S0020-1693(00)90938-1

upstream raw materials:

{Pt2Cl2(μ-Cl)2(PMePh2)2}

dichloro(1,5-cyclooctadiene)platinum(ll)

diphenyl(methyl)phosphine

trans-dichloro-((Ph₃)phosphine)(carbonyl)platinum(II)

Downstream raw materials:

trans-dichloro-((Me)(Ph₂)phosphine)(carbonyl)platinum(II)

(C₆H₅)2CH₃PPt(CO)Cl(C₆H₂(CH₃)3)

(C₆H₅)2CH₃PPt(CO)Cl(C₆H₂(CH₃)3)

2,4,6-(CH₃)3C₆H₂HgCl

Refernces

• 1、 Anderson,Clark,Davies. "Reactivity of platinum diolefin complexes. Roles of trans influence and chelate effect". . p. 1636 - 1639. Retrieved 2008/10/08.
• 2、 Anderson, Gordon K.,Cross, Ronald J.. "Preparation of the Complexes trans- and their Isomerisation to cis Isomers". . p. 1988 - 1991. Retrieved 2007/10/02.