trans dibromobispyridine palladium (II)

Base Information

• Chemical Name: trans dibromobispyridine palladium (II)
• CAS No.: 15227-49-3
• Molecular Formula: C₁₀H₁₀Br₂N₂Pd
• Molecular Weight: 424.431
• Mol file: 15227-49-3.mol

Synonyms:

Chemical Property of trans dibromobispyridine palladium (II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of trans dibromobispyridine palladium (II)

There total 3 articles about trans dibromobispyridine palladium (II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

pyridine (110-86-1) + 3-(2-fluorobenzyl)-1-(4-methoxyphenyl)-1H-imidazolium bromide + potassium bromide (7558-02-3,7758-02-3) + palladium dichloride → trans dibromobispyridine palladium (II) (15227-49-3,70494-44-9,14024-86-3) + [Pd(3-(2-fluorobenzyl)-1-(4-methoxyphenyl)-1H-imidazolline-2-ylidene)Br2(pyridine)]

Guidance literature:

With potassium carbonate; at 80 ℃; for 48h;

DOI:10.1007/s12039-020-1754-y

Reference yield: 40.0%

C42H38BrN3O7Pd → trans dibromobispyridine palladium (II) (15227-49-3,70494-44-9,14024-86-3) + (E)-dimethyl 1-(N,N'-bis(3-methoxyphenyl)carbamimidoyl)-9-methoxy-2,4-diphenyl-1H-benzo[b]azepine-3,5-dicarboxylate

Guidance literature:

With pyridine; for 5h; Reflux;

DOI:10.1021/om500837v

Reference yield:

2C5H5NH(1+)*PdBr4(2-)=(C5H5NH)2[PdBr4] → trans dibromobispyridine palladium (II) (15227-49-3,70494-44-9,14024-86-3) + palladium (7440-05-3) + palladium(II) bromide (13444-94-5)

Guidance literature:

In neat (no solvent); byproducts: HBr; isothermal decompn. at 180°C; elem. anal.;

upstream raw materials:

pyridine

potassium bromide