1-Propenylpropyl ether

Base Information

• Chemical Name: 1-Propenylpropyl ether
• CAS No.: 21087-24-1
• Molecular Formula: C₆H₁₂O
• Molecular Weight: 100.161
• DSSTox Substance ID: DTXSID801022516
• Nikkaji Number: J1.336.128B
• Wikidata: Q76305329
• Mol file: 21087-24-1.mol

Synonyms:74499-33-5;Ether,1- propenyl propyl;3424-89-3;1-Propenylpropyl ether;Ether, propenyl propyl;trans-propenylpropyl ether;21087-24-1;NTXOAYYHJHJLCN-HWKANZROSA-N;DTXSID801022516;(1E)-1-Propenyl propyl ether #;(1E)-1-PROPOXYPROP-1-ENE

Chemical Property of 1-Propenylpropyl ether

Chemical Property:

• XLogP3: 2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 100.088815002
• Heavy Atom Count: 7
• Complexity: 48.1

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Chemical Classes: UVCB
• Canonical SMILES: CCCOC=CC
• Isomeric SMILES: CCCO/C=C/C

Technology Process of 1-Propenylpropyl ether

There total 2 articles about 1-Propenylpropyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1-dipropoxypropane (4744-11-0) → cis-propenyl propyl ether (14360-78-2) + (E)-1-Propoxy-propene (21087-24-1)

Guidance literature:

With kaolin; at 300 - 450 ℃;

Reference yield:

acrolein dipropylacetal (20615-55-8) → cis-propenyl propyl ether (14360-78-2) + (E)-1-Propoxy-propene (21087-24-1)

Guidance literature:

at 450 ℃; for 0.00416667h;

DOI:10.1016/S0040-4020(01)97844-5

Reference yield:

(E)-1-Propoxy-propene (21087-24-1) → N-[2-(5t-methyl-1,3-diphenyl-6c-propoxy-1,4,5,6-tetrahydro-pyrano[2,3-c]pyrazol-4r-yl)-phenyl]-acetamide

Guidance literature:

Multi-step reaction with 3 steps

1: 8 h / 80 °C

2: H₂ / Pd-C / ethanol

3: 1 h / 70 °C

With hydrogen; palladium on activated charcoal; In ethanol;

upstream raw materials:

1,1-dipropoxypropane

acrolein dipropylacetal

Downstream raw materials:

5t-methyl-4r-(2-nitro-phenyl)-1,3-diphenyl-6c-propoxy-1,4,5,6-tetrahydro-pyrano[2,3-c]pyrazole