4744-11-0

Usage

InChI:InChI=1/C9H20O2/c1-4-7-10-9(6-3)11-8-5-2/h9H,4-8H2,1-3H3

Upstream product

• 71-23-8 propan-1-ol 
• 762243-62-9 N-allyl-N-phenylpivalamide 
• 214766-83-3 4-bromo-N-allyl-N-methyl-benzamide 
• 114908-29-1 Benzo[1,3]dioxole-5-carboxylic acid allyl-methyl-amide 
• 56-23-5 tetrachloromethane 

Downstream Products

• 14360-78-2 cis-propenyl propyl ether 
• 21087-24-1 (E)-1-Propoxy-propene 
• 14250-96-5 2-methyl-2-pentenal 
• 104-46-1 anethole 
• 2568-96-9 2-ethyl-1,3-dioxolane 
• 71-23-8 propan-1-ol 
• 78706-60-2 2-[1-(2-hydroxy-ethoxy)-propoxy]-ethanol 

Relevant academic research and scientific papers

Photocatalytic Conversion of a FeCl3–CCl4–ROH System

The photocatalytic transformations of carbon tetrachloride and aliphatic primary alcohols in the presence of iron trichloride and a molar ratio of components FeCl3: CCl4: ROH = 1: 300: 2550 were studied. CCl4 is transformed into chloroform and hexachloroethane after exposure to a mercury lamp (250 W) to the FeCl3–CCl4–ROH system at 20°C, whereas the primary ROH alcohols are selectively oxidized into acetals (1,1-dialkoxyalkanes). The maximum conversion of CCl4 reaches 80%. The kinetics and mechanism of the photocatalytic conversion of the FeCl3–CCl4–ROH system are considered.

One-step RhCl3-catalyzed deprotection of acyclic N-allyl amides

(Chemical Equation Presented) A convenient one-step RhCl 3-catalyzed deprotection of acyclic N-allyl amides is described. Preliminary mechanistic studies reveal that the key to the success of the one-step deprotection process is the dual function of RhCl3 in alcohol solvents. Reaction of RhCl3 with n-PrOH not only provides an active rhodium hydride species to catalyze isomerization of N-allyl amides to corresponding enamides but also generates a crucial catalytic amount of HCl to convert the enamides to deallylated amides through N,O-acetal exchange.