3α,6α-bis(benzoyloxy)-5α-cholestane-7β,15α-diol

Base Information

Chemical Name:3α,6α-bis(benzoyloxy)-5α-cholestane-7β,15α-diol
CAS No.:336100-02-8
Molecular Formula:C₄₁H₅₆O₆
Molecular Weight:644.892
Hs Code.:

Synonyms:

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Chemical Property of 3α,6α-bis(benzoyloxy)-5α-cholestane-7β,15α-diol

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Technology Process of 3α,6α-bis(benzoyloxy)-5α-cholestane-7β,15α-diol

There total 11 articles about 3α,6α-bis(benzoyloxy)-5α-cholestane-7β,15α-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 336100-33-5
3α,6α,7β-tris(benzoyloxy)-5α-cholest-14-ene

: 336100-02-8
3α,6α-bis(benzoyloxy)-5α-cholestane-7β,15α-diol

Guidance literature:: 3α,6α,7β-tris(benzoyloxy)-5α-cholest-14-ene; With borane-THF; In tetrahydrofuran; at 25 ℃; for 3h;

With sodium perborate; In tetrahydrofuran; water; at 25 ℃;
DOI:10.1016/S0040-4020(00)01086-3

Reference yield:

: 809-51-8
7-ketocholesteryl acetate

: 336100-02-8
3α,6α-bis(benzoyloxy)-5α-cholestane-7β,15α-diol

Guidance literature:: Multi-step reaction with 10 steps

1.1: 93 percent / CeCl₃*7H₂O; NaBH₄ / CH₂Cl₂; methanol / -78 - 20 °C

2.1: 93 percent / DMAP / pyridine / 25 °C

3.1: BH₃*THF / tetrahydrofuran / 0 - 25 °C

3.2: 80 percent / 30 percent H₂O₂; 10 percent NaOH / tetrahydrofuran / 2 h / 0 °C

4.1: 100 percent / TMSOTf / CH₂Cl₂ / 0.5 h / 25 °C

5.1: 92 percent / 10 percent NaOH / ethanol; tetrahydrofuran / 1 h / 0 °C

6.1: 87 percent / PPh₃; DEAD / tetrahydrofuran / 0.08 h / 25 °C

7.1: 68 percent / benzene / 25 °C / Photolysis

8.1: LiAlH₄ / tetrahydrofuran / 0.25 h / 25 °C

8.2: 91 percent / aq. NaOH / 0 - 25 °C

9.1: 91 percent / TMSOTf / CH₂Cl₂ / 1 h / 25 °C

10.1: BH₃*THF / tetrahydrofuran / 3 h / 25 °C

10.2: sodium perborate / tetrahydrofuran; H₂O / 25 °C

With dmap; sodium hydroxide; sodium tetrahydroborate; lithium aluminium tetrahydride; cerium(III) chloride; borane-THF; trimethylsilyl trifluoromethanesulfonate; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; pyridine; methanol; ethanol; dichloromethane; benzene; 1.1: Luche reduction / 6.1: Mitsunobu reaction;
DOI:10.1016/S0040-4020(00)01086-3

Reference yield:

: 202416-16-8
5α-cholestane-3β,6α,7β-triol

: 336100-02-8
3α,6α-bis(benzoyloxy)-5α-cholestane-7β,15α-diol

Guidance literature:: Multi-step reaction with 7 steps

1.1: 100 percent / TMSOTf / CH₂Cl₂ / 0.5 h / 25 °C

2.1: 92 percent / 10 percent NaOH / ethanol; tetrahydrofuran / 1 h / 0 °C

3.1: 87 percent / PPh₃; DEAD / tetrahydrofuran / 0.08 h / 25 °C

4.1: 68 percent / benzene / 25 °C / Photolysis

5.1: LiAlH₄ / tetrahydrofuran / 0.25 h / 25 °C

5.2: 91 percent / aq. NaOH / 0 - 25 °C

6.1: 91 percent / TMSOTf / CH₂Cl₂ / 1 h / 25 °C

7.1: BH₃*THF / tetrahydrofuran / 3 h / 25 °C

7.2: sodium perborate / tetrahydrofuran; H₂O / 25 °C

With sodium hydroxide; lithium aluminium tetrahydride; borane-THF; trimethylsilyl trifluoromethanesulfonate; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; ethanol; dichloromethane; benzene; 3.1: Mitsunobu reaction;
DOI:10.1016/S0040-4020(00)01086-3