[Ru2(CO)4(μ-H)(μ-P(t-Bu)2)(μ-di(phenylphosphino)methane)(trans-μ-η2-ONNO)]

Base Information

• Chemical Name: [Ru2(CO)4(μ-H)(μ-P(t-Bu)2)(μ-di(phenylphosphino)methane)(trans-μ-η2-ONNO)]
• CAS No.: 671773-85-6
• Molecular Formula: C₃₇H₄₁N₂O₆P₃Ru₂
• Molecular Weight: 904.804
• Mol file: 671773-85-6.mol

Synonyms:

Chemical Property of [Ru2(CO)4(μ-H)(μ-P(t-Bu)2)(μ-di(phenylphosphino)methane)(trans-μ-η2-ONNO)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru2(CO)4(μ-H)(μ-P(t-Bu)2)(μ-di(phenylphosphino)methane)(trans-μ-η2-ONNO)]

There total 1 articles about [Ru2(CO)4(μ-H)(μ-P(t-Bu)2)(μ-di(phenylphosphino)methane)(trans-μ-η2-ONNO)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

[Ru2(CO)4(μ-H)(μ-P(t)Bu2)(μ-dppm)] (225092-99-9) + nitrogen(II) oxide (10102-43-9) → [Ru2(CO)4(μ-H)(μ-P(t-Bu)2)(μ-di(phenylphosphino)methane)(trans-μ-η2-ONNO)] (671773-85-6)

Guidance literature:

In toluene; under Ar, Schlenk technique; soln. of complex was cooled to -60°Cand slow stream of NO was bubbled through soln. for ca. 10 min, mixt. w as warmed to room temp. by stirring for 30 min; solid was filtered, washed with hexane, dried under vac., recrystd. fromCH2Cl2/hexane; elem. anal.;

DOI:10.1021/om030618s

Reference yield:

[Ru2(CO)4(μ-H)(μ-P(t-Bu)2)(μ-di(phenylphosphino)methane)(trans-μ-η2-ONNO)] (671773-85-6) + trimethoxonium tetrafluoroborate (420-37-1) → [Ru2(CO)4(μ-H)(μ-P(t-Bu)2)(μ-dppm)(μ-η2-ONNOMe)][BF4]

Guidance literature:

In dichloromethane; under Ar: (Me3O)BF4 added to soln. of Ru complex in CH2Cl2, mixt. stirred for 1 h at room temp.; evapn. in vacuo;

DOI:10.1016/j.ica.2009.11.008

upstream raw materials:

[Ru2(CO)4(μ-H)(μ-P(t)Bu2)(μ-dppm)]

nitrogen(II) oxide

Refernces