(η5-C5Me5)Ru(CO)2hydride

Base Information

• Chemical Name: (η5-C5Me5)Ru(CO)2hydride
• CAS No.: 82728-97-0
• Molecular Formula: C₁₂H₁₆O₂Ru
• Molecular Weight: 293.328
• Mol file: 82728-97-0.mol

Synonyms:

Chemical Property of (η5-C5Me5)Ru(CO)2hydride

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η5-C5Me5)Ru(CO)2hydride

There total 2 articles about (η5-C5Me5)Ru(CO)2hydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

9,10-dihydroanthracene (613-31-0) + (C5(CH3)5)Ru(CO)(P(CH3)2C6H5)CHO (88296-35-9) → (η5-C5Me5)Ru(CO)2hydride (82728-97-0) + (C5(CH3)5)Ru(CO)(P(CH3)2C6H5)H (88296-36-0)

Guidance literature:

In benzene-d6; under vac.; 40°C; 14 days;

DOI:10.1021/ja00314a035

Reference yield:

iodo(cyclopentadienyl)dicarbonylruthenium(II) + (C5(CH3)5)Ru(CO)(P(CH3)2C6H5)CHO (88296-35-9) → dicarbonyl(cyclopentadienyl)hydridoruthenium + (η5-C5Me5)Ru(CO)2hydride (82728-97-0) + (C5(CH3)5)Ru(CO)(P(CH3)2C6H5)I (103817-62-5) + (C5(CH3)5)Ru(CO)2(P(CH3)2C6H5)(1+)*I(1-)=(C5(CH3)5)Ru(CO)2(P(CH3)2C6H5)(1+)I(1-) (88296-33-7)

Guidance literature:

In benzene; stirring (overnight), heating (65°C, 15 min); solvent removal (vac.); (1)H-NMR;

Reference yield: 68.0%

(η5-C5Me5)Ru(CO)2hydride (82728-97-0) + dichlorodiphenylgermane (1613-66-7) → (CH3)5C5Ru(CO)2Ge(C6H5)2Cl

Guidance literature:

With n-butyllithium; In tetrahydrofuran; (Ar); to a soln. of Ru complex in THF BuLi added at -45°C, mixt. stirred for 30 min; Ge compd. added, mixt. stirred for -45°C for 30 min, warmed up to room temp., stirred for 1 h; the react. mixt. placed on silica gel flash column, eluent toluene- hexane (1:1); solvent from fraction removed afforded a powder; elem. anal;

DOI:10.1016/S0022-328X(01)01373-0

upstream raw materials:

9,10-dihydroanthracene

(C₅(CH₃)5)Ru(CO)(P(CH₃)2C₆H₅)CHO

Downstream raw materials:

(CH₃)5C₅Ru(CO)2Si(C₆H₄CH₃)2H