C₂₅H₃₄Cl₃NO₆Si

Base Information

Chemical Name:C₂₅H₃₄Cl₃NO₆Si
CAS No.:1421851-18-4
Molecular Formula:C₂₅H₃₄Cl₃NO₆Si
Molecular Weight:578.993
Hs Code.:

C<sub>25</sub>H<sub>34</sub>Cl<sub>3</sub>NO<sub>6</sub>Si

Synonyms:

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Chemical Property of C₂₅H₃₄Cl₃NO₆Si

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Technology Process of C₂₅H₃₄Cl₃NO₆Si

There total 7 articles about C₂₅H₃₄Cl₃NO₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1421851-06-0
N-((1R,2S,3R,6S)-2-(benzyloxy)-4-(dimethoxymethyl)-3-formyl-6-methyl-7-oxabicyclo[4.1.0]heptan-3-yl)-2,2,2-trichloroacetamide

: 1066-54-2
trimethylsilylacetylene

: 1421851-18-4
C₂₅H₃₄Cl₃NO₆Si

Guidance literature:: trimethylsilylacetylene; With ethylmagnesium bromide; In tetrahydrofuran; at 20 ℃; for 0.25h; Cooling with ice; Inert atmosphere;

N-((1R,2S,3R,6S)-2-(benzyloxy)-4-(dimethoxymethyl)-3-formyl-6-methyl-7-oxabicyclo[4.1.0]heptan-3-yl)-2,2,2-trichloroacetamide; In tetrahydrofuran; at -20 - 20 ℃; for 1h; stereoselective reaction; Inert atmosphere;
DOI:10.1021/jo302773f

Reference yield:

: 1421851-02-6
2,2,2-trichloro-N-((1R)-6-(dimethoxymethyl)-4-methyl-2-oxo-1-vinylcyclohex-3-en-1-yl)acetamide

: 1421851-18-4
C₂₅H₃₄Cl₃NO₆Si

Guidance literature:: Multi-step reaction with 5 steps

1.1: diisobutylaluminium hydride / dichloromethane; toluene / 0.5 h / -78 °C / Inert atmosphere

2.1: disodium hydrogenphosphate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 30 h / 20 °C / Inert atmosphere

3.1: sodium hydride / tetrahydrofuran; N,N-dimethyl-formamide / 0.5 h / 20 °C / Inert atmosphere

3.2: 10 h

4.1: ozone / dichloromethane / 1.5 h / -78 °C / Inert atmosphere

4.2: -78 - 20 °C / Inert atmosphere

5.1: ethylmagnesium bromide / tetrahydrofuran / 0.25 h / 20 °C / Cooling with ice; Inert atmosphere

5.2: 1 h / -20 - 20 °C / Inert atmosphere

With disodium hydrogenphosphate; ethylmagnesium bromide; sodium hydride; diisobutylaluminium hydride; ozone; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jo302773f

Reference yield:

: C₁₂H₁₂Cl₃NO₃

: 1421851-18-4
C₂₅H₃₄Cl₃NO₆Si

Guidance literature:: Multi-step reaction with 6 steps

1.1: CSA / methanol / 1 h / 20 °C / Inert atmosphere

2.1: diisobutylaluminium hydride / dichloromethane; toluene / 0.5 h / -78 °C / Inert atmosphere

3.1: disodium hydrogenphosphate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 30 h / 20 °C / Inert atmosphere

4.1: sodium hydride / tetrahydrofuran; N,N-dimethyl-formamide / 0.5 h / 20 °C / Inert atmosphere

4.2: 10 h

5.1: ozone / dichloromethane / 1.5 h / -78 °C / Inert atmosphere

5.2: -78 - 20 °C / Inert atmosphere

6.1: ethylmagnesium bromide / tetrahydrofuran / 0.25 h / 20 °C / Cooling with ice; Inert atmosphere

6.2: 1 h / -20 - 20 °C / Inert atmosphere

With disodium hydrogenphosphate; ethylmagnesium bromide; sodium hydride; diisobutylaluminium hydride; ozone; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jo302773f