PdCl[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]PPh3

Base Information

• Chemical Name: PdCl[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]PPh3
• CAS No.: 336613-35-5
• Molecular Formula: C₂₉H₂₉ClNO₃PPd
• Molecular Weight: 612.401
• Mol file: 336613-35-5.mol

Synonyms:

Chemical Property of PdCl[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]PPh3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PdCl[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]PPh3

There total 3 articles about PdCl[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]PPh3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.7%

[Pd(μ-Cl)[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]]2 (336613-31-1) + triphenylphosphine (603-35-0) → PdCl[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]PPh3 (336613-35-5)

Guidance literature:

In dichloromethane; suspn. of Pd complex treated with PPh3, stirred at room temp. for 1.5 h; evapd., pptd.(Et2O), filtered, washed (Et2O), air dried, elem. anal.;

DOI:10.1039/b006140i

Reference yield:

[Pd(μ-OAc)[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]]2 (336613-29-7) → PdCl[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]PPh3 (336613-35-5)

Guidance literature:

Multi-step reaction with 2 steps

1: methanol

2: dichloromethane

In methanol; dichloromethane;

DOI:10.1039/b006140i

Reference yield:

C6H3-3,4-(CH3O)2-C(H)=NCH2CH2OH → PdCl[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]PPh3 (336613-35-5)

Guidance literature:

Multi-step reaction with 3 steps

1: methanol

2: methanol

3: dichloromethane

In methanol; dichloromethane;

DOI:10.1039/b006140i

upstream raw materials:

[Pd(μ-Cl)[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]]2

triphenylphosphine

[Pd(μ-OAc)[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]]2

Downstream raw materials:

Pd[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N,O](PPh3)ClO4