Pd[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N,O](PPh3)ClO4

Base Information

• Chemical Name: Pd[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N,O](PPh3)ClO4
• CAS No.: 336613-49-1
• Molecular Formula: C₂₉H₂₉NO₃PPd*ClO₄
• Molecular Weight: 676.399
• Mol file: 336613-49-1.mol

Synonyms:

Chemical Property of Pd[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N,O](PPh3)ClO4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pd[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N,O](PPh3)ClO4

There total 6 articles about Pd[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N,O](PPh3)ClO4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.4%

PdCl[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]PPh3 (336613-35-5) + silver perchlorate → Pd[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N,O](PPh3)ClO4 (336613-49-1)

Guidance literature:

In acetone; suspn. of Pd complex mixed with AgClO4, stirred at room temp. for 30 min(in the dark); filtered, evapd., pptd.(Et2O), stirred, filtered, air dried, elem. anal.;

DOI:10.1039/b006140i

Reference yield: 81.5%

Pd[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N,O](NCMe)ClO4 (336613-44-6) + triphenylphosphine (603-35-0) → Pd[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N,O](PPh3)ClO4 (336613-49-1)

Guidance literature:

In dichloromethane; suspn. of Pd complex mixed with PPh3, stirred at room temp. for 15 min; evapd., pptd.(Et2O), stirred, filtered, air dried, elem. anal.;

DOI:10.1039/b006140i

Reference yield:

C6H3-3,4-(CH3O)2-C(H)=NCH2CH2OH → Pd[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N,O](PPh3)ClO4 (336613-49-1)

Guidance literature:

Multi-step reaction with 4 steps

1: methanol

2: methanol

3: acetonitrile

4: dichloromethane

In methanol; dichloromethane; acetonitrile;

DOI:10.1039/b006140i

upstream raw materials:

PdCl[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]PPh3

Pd[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N,O](NCMe)ClO4

triphenylphosphine

[Pd(μ-Cl)[C6H2-4,5-(CH3O)2-2-C(H)=NCH2CH2OH-κ-C1,N]]2