N-(4-phenyl-N-(4,4'-bipyridinium))ferrocene nitrate

Base Information

• Chemical Name: N-(4-phenyl-N-(4,4'-bipyridinium))ferrocene nitrate
• CAS No.: 1355074-19-9
• Molecular Formula: C₂₆H₂₁FeN₂*NO₃
• Molecular Weight: 479.318
• Mol file: 1355074-19-9.mol

Synonyms:

Chemical Property of N-(4-phenyl-N-(4,4'-bipyridinium))ferrocene nitrate

Chemical Property:

Purity/Quality:

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Technology Process of N-(4-phenyl-N-(4,4'-bipyridinium))ferrocene nitrate

There total 1 articles about N-(4-phenyl-N-(4,4'-bipyridinium))ferrocene nitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

4-ferrocenylaniline + 1-(2,4-dinitrophenyl)-4,4'-bipyridinium chloride (71190-35-7) + potassium nitrate → N-(4-phenyl-N-(4,4'-bipyridinium))ferrocene nitrate (1355074-19-9)

Guidance literature:

In ethanol; acetonitrile; a soln. of complex and bipyridine-compound in CH3CN/C2H5OH = 1/3 was refluxed with stirring for 16 h, cooled; the solvent was removed under reduced pressure, column chromy. on silicagel, (THF/H2O/KNO3 = 100/20/4); elem. anal.;

DOI:10.1021/ja209766e

Reference yield: 60.0%

potassium hexafluorophosphate (17084-13-8) + N-(4-phenyl-N-(4,4'-bipyridinium))ferrocene nitrate (1355074-19-9) + methyl iodide (74-88-4) → N-(4-ferrocenylphenyl)-N'-methyl-4,4'-bipyridinium bis(hexafluorophosphate)

Guidance literature:

In dichloromethane; acetonitrile; CH3I was added dropwise to a degassed soln. of complex in CH3CN-CH2Cl2, stirred under Ar in the dark at 70°C for 24 h, ppt. was washed with CH3CN, dissolved in min H2O, an aq. satd. KPF6 was added; filtered, washed with water, dried;

DOI:10.1021/ja209766e

upstream raw materials:

1-(2,4-dinitrophenyl)-4,4'-bipyridinium chloride