(η6-benzyl 1-phenylethyl ether)tricarbonylchromium(O)

Base Information

• Chemical Name: (η6-benzyl 1-phenylethyl ether)tricarbonylchromium(O)
• CAS No.: 89974-34-5
• Molecular Formula: C₁₈H₁₆CrO₄
• Molecular Weight: 348.319
• Mol file: 89974-34-5.mol

Synonyms:

Chemical Property of (η6-benzyl 1-phenylethyl ether)tricarbonylchromium(O)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (η6-benzyl 1-phenylethyl ether)tricarbonylchromium(O)

There total 2 articles about (η6-benzyl 1-phenylethyl ether)tricarbonylchromium(O) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

(dibenzyl ether)tricarbonylchromium(0) (86567-40-0) + methyl iodide (74-88-4) → (η6-benzyl 1-phenylethyl ether)tricarbonylchromium(O) (89974-34-5,177034-35-4,185999-36-4)

Guidance literature:

With methanol; n-butyllithium; In tetrahydrofuran; addn. of Bu-Li in hexane to soln. of Cr complex in THF at -40°C under N2 atmosphere, stirring for 1 h, addn. of MeI, stirring for 1 h, addn. of CH3OH, warming to 20°C, evaporation of solvent, extraction with Et2O; mechanism discussed;; column chromatography on Al2O3 with CH2Cl2, removal of solvent; elem. anal.;;

Reference yield:

(dibenzyl ether)tricarbonylchromium(0) (86567-40-0) → (η6-benzyl 1-phenylethyl ether)tricarbonylchromium(O) (89974-34-5,177034-35-4,185999-36-4)

Guidance literature:

With n-butyllithium; methyl iodide; In not given; treatment of Cr-complex with BuLi, then addn. of MeI;

DOI:10.1039/c39830001316

upstream raw materials:

(dibenzyl ether)tricarbonylchromium⁽⁰⁾

methyl iodide