(ruthenium(IV))(C5(Me)5)Cl(acetonitrile)(η3-C6H5CHCHCH2)PF6

Base Information

Chemical Name:(ruthenium(IV))(C5(Me)5)Cl(acetonitrile)(η3-C6H5CHCHCH2)PF6
CAS No.:916595-28-3
Molecular Formula:C₂₁H₂₇ClNRu*F₆P
Molecular Weight:574.939
Hs Code.:

Synonyms:

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Chemical Property of (ruthenium(IV))(C5(Me)5)Cl(acetonitrile)(η3-C6H5CHCHCH2)PF6

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Technology Process of (ruthenium(IV))(C5(Me)5)Cl(acetonitrile)(η3-C6H5CHCHCH2)PF6

There total 1 articles about (ruthenium(IV))(C5(Me)5)Cl(acetonitrile)(η3-C6H5CHCHCH2)PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 21087-29-6
trans-3-phenylprop-2-enyl chloride

: tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate

: 916595-28-3,838828-11-8,838874-55-8
[Ru(η5-C5Me5)Cl(η3-phenylallyl)(CH3CN)](PF6)

Guidance literature:: In dichloromethane; 1.2 equiv of C6H5CHCHCH2Cl was added to a stirred soln. of complex in CH2Cl2, stirred at room temp. overnight; reduced in vol. under vac., diethyl ether was added, ppt. was washed with diethyl ether, dried under vac.; elem. anal.;
DOI:10.1021/om049057a

Reference yield: 91.0%

: 630-18-2
tert-butyl isocyanide

: 838828-11-8,838874-55-8,916595-28-3
(ruthenium(IV))(C5(Me)5)Cl(acetonitrile)(η3-C6H5CHCHCH2)PF6

: 911858-92-9,911815-58-2
[RuCp*Cl((CH3)3CCN)(η3-CH2-CH-CHPh)](PF6)

Guidance literature:: In neat (no solvent); under N2 atm. soln. Ru complex in tert-butylcarbonitrile was stirred for2 h; soln. was concd. in vacuo; elem. anal.;
DOI:10.1021/om060448u

Reference yield: 84.0%

: 26042-63-7
silver(I) hexafluorophosphate

: 838828-11-8,838874-55-8,916595-28-3
(ruthenium(IV))(C5(Me)5)Cl(acetonitrile)(η3-C6H5CHCHCH2)PF6

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: (ruthenium(IV))(C5(Me)5)(dmf)2(η3-C6H5CHCHCH2)(PF6)2

Guidance literature:: In N,N-dimethyl-formamide; byproducts: AgCl; mixt. stirred for 16 h; soln. filtered, slowly concd. under vac., washed with diethyl ether, dissolved (dichloromethane), filtered, dried under vac. (sequence repeated one more time);
DOI:10.1002/anie.200600447