[Re₂(CO)₈(CH₃CN)₂]

Base Information

• Chemical Name: [Re₂(CO)₈(CH₃CN)₂]
• CAS No.: 83214-32-8
• Molecular Formula: C₁₂H₆N₂O₈Re₂
• Molecular Weight: 678.602
• Mol file: 83214-32-8.mol

Synonyms:

Chemical Property of [Re₂(CO)₈(CH₃CN)₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Re₂(CO)₈(CH₃CN)₂]

There total 1 articles about [Re₂(CO)₈(CH₃CN)₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Re2(CO)9CH3CN (139406-04-5,67486-88-8) → decacarbonyldirhenium(0) (14285-68-8) + tetrahydroxyl tetrarhenium dodecacarbonyl + bis(acetonitrile)octacarbonyldirhenium (139575-85-2,145306-70-3,83214-32-8)

Guidance literature:

With water; In not given; Irradiation (UV/VIS); Sunlamp photolysis in THF or heptane soln.;; detected by IR spectra;;

DOI:10.1021/om00069a007

Reference yield: 81.0%

[Re2(CO)8(CH3CN)2] (145306-70-3,83214-32-8,139575-85-2) + Benzeneselenol (645-96-5) → [(CO)4Re(μ-benzeneselenolate)]2 (15213-37-3) + Re2(μ-H)(μ-SePh)(CO)8 (372488-24-9)

Guidance literature:

In toluene; byproducts: CH3CN; under Ar, 80 °C for 30 min; soln. was cooled to room temp., evapd. to dryness, residue was taken in CH2Cl2, chromy. (CH2Cl2/n-hexane=1:5), elem. anal.;

DOI:10.1002/1521-3749(200109)627:9<2295::AID-ZAAC2295>3.0.CO;2-#

Reference yield: 80.0%

Cyclohexanethiol (1569-69-3) + [Re2(CO)8(CH3CN)2] (145306-70-3,83214-32-8,139575-85-2) → (CO)4Re(μ-H)(μ-S(cyclohexyl))Re(CO)4 (249751-75-5)

Guidance literature:

In toluene; dissoln. of the thiol and the Re complex in toluene with subsequent heating to 80°C (max. 30 min); solvent removal, chromy. (gypsum/silica plates; CH2Cl2/n-hexane), crystn. (CHCl3/n-pentane); elem. anal.;

DOI:10.1039/a905111b

upstream raw materials:

Re₂(CO)9CH₃CN

Downstream raw materials:

acetonitrile

(CO)4Re(μ-H)(μ-S(cyclohexyl))Re(CO)4

(CO)4Re(H)(SC₆F₅)Re(CO)4

(CO)4Re(μ-H)(μ-SPh)Re(CO)4