ferryltetraphenylporphyrin-[⁽¹⁸⁾O]

Base Information

• Chemical Name: ferryltetraphenylporphyrin-[⁽¹⁸⁾O]
• CAS No.: 144473-57-4
• Molecular Formula: C₄₄H₂₈FeN₄O
• Molecular Weight: 686.58
• Mol file: 144473-57-4.mol

Synonyms:

Chemical Property of ferryltetraphenylporphyrin-[⁽¹⁸⁾O]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ferryltetraphenylporphyrin-[⁽¹⁸⁾O]

There total 3 articles about ferryltetraphenylporphyrin-[⁽¹⁸⁾O] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5,10,15,20-tetraphenyl iron porphyrin (16591-56-3) + oxygen-18 (32767-18-3) → ferryltetraphenylporphyrin-[(18)O] (144473-57-4)

Guidance literature:

In solid matrix; Irradiation (UV/VIS); cocondensation at .approx.15 K, 406.7-nm excitation; detected by Raman spectroscopy;

DOI:10.1021/ja00322a056

Reference yield:

bis(piperidine)(5,10,15,20-tetraphenylporphyrinato)iron(II) (17845-65-7) + oxygen-18 (32767-18-3) → oxoferryl 5,10,15,10-tetraphenylporphyrine (144473-57-4) + oxoferryl 5,10,15,10-tetraphenylporphyrine radical cation

Guidance literature:

In neat (no solvent); other Radiation; heated to 450 K under vacuum (10E-5 torr); vaporized at 500-600 K; cocondensed with dioxygen on the surface cooled to 30 K; laser irradiation;; identified by Raman spectroscopy;;

Reference yield:

oxygen + dioxygen-(16)O (1173018-52-4) + 5,10,15,20-tetraphenyl iron porphyrin (16591-56-3) + oxygen-18 (32767-18-3) → ferryltetraphenylporphyrin-[(16)O] + ferryltetraphenylporphyrin-[(18)O] (144473-57-4)

Guidance literature:

In solid matrix; Irradiation (UV/VIS); cocondensation at .approx.15 K, 406.7-nm excitation; detected by Raman spectroscopy;

DOI:10.1021/ja00322a056

upstream raw materials:

bis(piperidine)(5,10,15,20-tetraphenylporphyrinato)iron(II)

oxygen-18

dioxygen-⁽¹⁶⁾O

5,10,15,20-tetraphenyl iron porphyrin